Microscopic structural origin of slow dynamics in glass-forming liquids

Abstract

Supercooled liquids display sluggish dynamics, often attributed to their structural characteristics, yet the underlying mechanism remains elusive. Here we conduct numerical investigations into the structure–dynamics relationship in model glass-forming liquids, with a specific focus on an elementary particle rearrangement mode known as the ‘T1 process’. We discover that the ability of a T1 process to preserve glassy structural order before and after is pivotal towards determining a liquid’s fragility—whether it exhibits super-Arrhenius-like or Arrhenius-like behaviour. If a T1 process disrupts local structural order, it must occur independently without cooperativity, resulting in Arrhenius-like behaviour. By contrast, if it can maintain order, it sequentially propagates from disordered peripheries to the middle of high-structural-order regions, leading to cooperativity and super-Arrhenius-like behaviour. Our study establishes a microscopic link between liquid-structure ordering, dynamic cooperativity and super-Arrhenius-like dynamics, extending the understanding of the structure–dynamics relationships in supercooled liquids. An elementary particle rearrangement mode known as the T1 process links liquid dynamics and local structural ordering to understand the physical mechanisms of super-Arrhenius-like behaviour in glass-forming liquids.