{"title":"Novel organic molecular bridging strategy in Ti3CN interlayers towards stable and rapid sodium ions storage","authors":"Xiao-Rui Wang, Wen-Jie Shi, Ai-Jun Jiao, Zhen-Hai Fu, Min-Peng Li, Hong-Yan Li, Cai-Xia Zheng, Yu-Xia Hu, Hong-Tao Xue, Mao-Cheng Liu","doi":"10.1016/j.electacta.2025.145670","DOIUrl":null,"url":null,"abstract":"MXenes is considered as one of the most potential sodium ions storage materials due to its superior metallic conductivity, abundant surface functional groups, extensive specific surface area, and tunable interlayer spacing. Nevertheless, its practical application is hindered by severe volumetric expansion/shrinkage and slow sodium ions diffusion during sodium ions insertion/extraction process. Herein, a novel organic acid molecules bridging strategy is reported to stabilize layered structure and adjust the interlayer spacing of Ti<sub>3</sub>CN, which is realized by bridging organic acid molecules (named as TOAA) into Ti<sub>3</sub>CN interlayers (named as Ti<sub>3</sub>CN-TOAA) to form strong amido (HN-C=O) bonds. The carbonyl groups of TOAA molecules can not only provide active sites for sodium ions storage, but also inhibit volumetric expansion/shrinkage by providing strain/pillar effects within the Ti<sub>3</sub>CN interlayers, achieving stable and rapid sodium ions storage. Consequently, the interlayer spacing of Ti<sub>3</sub>CN-TOAA (1.42 nm) is enlargered compared with that of Ti<sub>3</sub>CN (1.22 nm), while the sodium ions migration barrier of Ti<sub>3</sub>CN-TOAA is reduced by 0.09 eV. Ti<sub>3</sub>CN-TOAA demonstrates superior cycling stability (the capacity retention remains at 83.2% after 2000 cycles at 0.5 A g<sup>-1</sup>) and rate capability (2.5 times the capacity of pristine Ti<sub>3</sub>CN at 5.0 A g<sup>-1</sup>). Significantly, the Ti<sub>3</sub>CN-TOAA||AC sodium ions capacitor (SIC) exhibits excellent cycling stability, retaining 79.3% of its capacity after 8000 cycles at 1.0 A g<sup>-1</sup>. This work presents a novel approach to achieving stable and rapid sodium ions storage by stabilizing layered structure and adjusting interlayer spacing.","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"35 1","pages":""},"PeriodicalIF":5.5000,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochimica Acta","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.electacta.2025.145670","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0
Abstract
MXenes is considered as one of the most potential sodium ions storage materials due to its superior metallic conductivity, abundant surface functional groups, extensive specific surface area, and tunable interlayer spacing. Nevertheless, its practical application is hindered by severe volumetric expansion/shrinkage and slow sodium ions diffusion during sodium ions insertion/extraction process. Herein, a novel organic acid molecules bridging strategy is reported to stabilize layered structure and adjust the interlayer spacing of Ti3CN, which is realized by bridging organic acid molecules (named as TOAA) into Ti3CN interlayers (named as Ti3CN-TOAA) to form strong amido (HN-C=O) bonds. The carbonyl groups of TOAA molecules can not only provide active sites for sodium ions storage, but also inhibit volumetric expansion/shrinkage by providing strain/pillar effects within the Ti3CN interlayers, achieving stable and rapid sodium ions storage. Consequently, the interlayer spacing of Ti3CN-TOAA (1.42 nm) is enlargered compared with that of Ti3CN (1.22 nm), while the sodium ions migration barrier of Ti3CN-TOAA is reduced by 0.09 eV. Ti3CN-TOAA demonstrates superior cycling stability (the capacity retention remains at 83.2% after 2000 cycles at 0.5 A g-1) and rate capability (2.5 times the capacity of pristine Ti3CN at 5.0 A g-1). Significantly, the Ti3CN-TOAA||AC sodium ions capacitor (SIC) exhibits excellent cycling stability, retaining 79.3% of its capacity after 8000 cycles at 1.0 A g-1. This work presents a novel approach to achieving stable and rapid sodium ions storage by stabilizing layered structure and adjusting interlayer spacing.
期刊介绍:
Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.