Redox-Enhanced Ionogels for Stretchable High-Energy Density Electrochemical Capacitors

IF 18.5 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Min Su Kim, Incheol Heo, Min Seok Kang, Bo Geun Jeon, Kyung Gook Cho, Won Cheol Yoo, Keun Hyung Lee
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Abstract

Developing stretchable energy storage devices with high energy and power densities poses a significant challenge for future wearable/deformable electronics. This study proposes new redox (R)-ionogels that incorporate organodisulfides as redox species for high-energy, stretchable redox-enhanced solid-state electrochemical capacitors (R-SECs). The R-SECs are prepared using R-ionogels made from tetraethylthiuram disulfide (TETDS), 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMI][TFSI]), and a physically crosslinked polymer network (poly(vinylidene fluoride-co-hexafluoropropylene), P(VDF-HFP)), sandwiched between two carbonaceous electrodes. Cyclic voltammetry and galvanostatic charge/discharge characteristics of the R-SECs demonstrated both effective redox reactions and non-faradaic capacitive energy storage. The optimized 0.25 M TETDS R-ionogel achieved a specific capacitance of 405 F g‒1, 83% rate retention, 80% cyclic stability after 2000 cycles, an energy density of 117 Wh kg‒1, and a power density of 5.9 kW kg‒1. Additionally, the 0.25 M TETDS enhanced the mechanical properties of the ionogel, increasing the strain at break from 1.92 to 3.25 and toughness from 0.38 to 1.35 MJ m⁻3. Finally, stretchable R-SECs possessing excellent stretching/releasing durability at 100% strain and volumetric energy densities 26.3 mWh cm−3 that surpass the upper bound of the Ragone plot for reported stretchable capacitors are successfully fabricated for the first time.

Abstract Image

用于可拉伸高能量密度电化学电容器的氧化还原增强离子凝胶
开发具有高能量和功率密度的可拉伸能量存储设备对未来的可穿戴/可变形电子产品提出了重大挑战。本研究提出了一种新的氧化还原(R)-离子凝胶,该凝胶将有机二硫化物作为氧化还原物质,用于高能、可拉伸的氧化还原增强固态电化学电容器(R- secs)。r - sec是用由四乙基硫脲二硫化(TETDS)、1-乙基-3-甲基咪唑二(三氟甲基磺酰基)亚胺([EMI][TFSI])和物理交联的聚合物网络(聚偏氟乙烯-共六氟丙烯,P(VDF-HFP))夹在两个碳质电极之间制成的r -离子凝胶制备的。循环伏安法和恒流充放电特性表明,r - sec具有有效的氧化还原反应和非法拉第电容储能特性。优化后的0.25 M TETDS r -离子凝胶的比电容为405 F - g-1,保留率为83%,循环2000次后的循环稳定性为80%,能量密度为117 Wh kg-1,功率密度为5.9 kW kg-1。此外,0.25 M TETDS增强了离子凝胶的力学性能,使断裂应变从1.92增加到3.25,韧度从0.38增加到1.35 MJ M⁻3。最后,研究人员首次成功制备了具有100%应变和26.3 mWh cm - 3体积能量密度的优异拉伸/释放耐久性的可拉伸r - sec,其体积能量密度超过了所报道的可拉伸电容器的Ragone图的上界。
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来源期刊
Advanced Functional Materials
Advanced Functional Materials 工程技术-材料科学:综合
CiteScore
29.50
自引率
4.20%
发文量
2086
审稿时长
2.1 months
期刊介绍: Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week. Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.
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