Sorghum grain as a bio-template: emerging, cost-effective, and metal-free synthesis of C-doped g-C3N4 for photo-degradation of antibiotic, bisphenol A (BPA), and phenol under solar light irradiation.

Abstract

Due to the industry's rapid growth, the presence of organic pollutants, especially antibiotics, in water and wastewater resources is the main concern for wildlife and human health. Therefore, these days, a significant challenge is developing an efficient, sustainable, and eco-friendly photocatalyst. Natural biological models have numerous advantages compared to artificial model materials. Biological models with unique multi-level structures and morphology can be used to create porous bio-templates to produce hierarchical materials. So, in this work, for the first time, this was achieved by using sorghum grain seeds as a bio-template (natural waste material) and urea as a precursor, through a simple and environmentally friendly method. We believed that natural waste materials with high carbon atom content could be used as both a carbon doping agent and a bio-template, thus improving the physical and optical properties of the resulting materials. In comparison to previous studies on the synthesis of C-doped g-C₃N₄, our work offers a greener and more cost-effective approach to synthesis, while also reducing waste material. We succeeded in the photo-degradation of a series of organic pollutants such as phenol, bisphenol A (BPA), and amoxicillin (AMX) in an aqueous solution under solar light illumination.