Comprehensive Insight Into Electronic Modulation of Rare-Earth Elements for Enhancing Electrocatalytic Performance of Atomically Dispersed Materials

IF 18.5 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Yanhui Cao, Xuerong Zheng, Yida Deng, Wenbin Hu
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引用次数: 0

Abstract

Atomically dispersed materials have been a thriving research field due to their maximum atomic utilization and remarkable performance in energy conversion and storage systems. Owing to the large atomic radius, strong oxophilicity, and unique electronic properties, rare-earth (RE) elements have been widely investigated as oxide carriers and promoters in atomically dispersed materials to manipulate and regulate the electronic structure of active species. Single-atom state with an adjustable coordination environment on the N-doped carbon endows RE metals with special electronic states and outstanding catalytic performances. A thorough comprehension of the electronic modulation mechanism of RE elements paves the way for the construction of advanced RE-based electrocatalysts with high activity, stability, and selectivity. This review provides a widespread insight into the roles of RE elements in modulating the electronic properties of atomically dispersed materials combined with the structure–performance relationship in electrocatalysis processes. The characteristic physical and chemical properties of RE elements are highlighted, and the synthetic strategy of RE-based atomically dispersed materials is discussed. Finally, a summary and perspectives for rational design and development of highly efficient RE-based catalysts are proposed. This review aims to provide a guideline for promoting the rational and effective utilization of RE elements in advanced functional materials.

Abstract Image

稀土元素电子调制提高原子分散材料电催化性能的综合研究
原子分散材料由于其在能量转换和存储系统中具有最大的原子利用率和卓越的性能而成为一个蓬勃发展的研究领域。由于具有较大的原子半径、较强的亲氧性和独特的电子性质,稀土元素作为氧化物载体和促进子在原子分散材料中被广泛研究,以操纵和调节活性物质的电子结构。在n掺杂碳上具有可调节配位环境的单原子态使得稀土金属具有特殊的电子态和优异的催化性能。深入了解稀土元素的电子调制机理,为构建具有高活性、稳定性和选择性的高级稀土基电催化剂铺平了道路。本文综述了稀土元素在调节原子分散材料电子性能中的作用,并结合电催化过程中的结构-性能关系。重点介绍了稀土元素特有的物理化学性质,讨论了稀土原子分散材料的合成策略。最后,对稀土基高效催化剂的合理设计和开发进行了总结和展望。本文旨在为推进稀土元素在先进功能材料中的合理有效利用提供指导。
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来源期刊
Advanced Functional Materials
Advanced Functional Materials 工程技术-材料科学:综合
CiteScore
29.50
自引率
4.20%
发文量
2086
审稿时长
2.1 months
期刊介绍: Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week. Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.
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