Comparative Study of Catalytic Performance of Post Treated H-BEA Zeolites for n-Hexyl Levulinate Synthesis from Renewable Feedstock

IF 2.3 4区化学 Q3 CHEMISTRY, PHYSICAL

Catalysis Letters Pub Date : 2025-01-03 DOI:10.1007/s10562-024-04903-8

Ayushikumari R. Patel, Aayushi Lodhi, Hemant Parmar, Ajay Dalai, Kalpana Maheria

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Abstract

In the present study, zeolite H-BEA catalyst has been modified by controlled desilication post modification route using first with cationic surfactant, (6-Bromohexyl)trimethylammonium Bromide (6-Br-TMA) designated as MBB catalyst and then the other with 6-Br-TMA and yeast, designated as MBBY catalyst. These newly synthesized catalytic materials have been characterized by several techniques such as, Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction, scanning electron microscopy, solid state NMR (²⁹Si, ²⁷Al, ¹H) N₂ sorption isotherm analysis, thermogravimetric analysis, ammonia temperature program desorption (NH₃-TPD) analysis, etc. These mesozeolites were found to exhibit enhanced physicochemical (BET surface area, surface acidity, pore volume, mesoporosity, etc.) characteristics as compared to their parent zeolite H-BEA. Catalytic assessement studies of the synthesized zeolites has been demonstrated via conducting experiments involving esterification of levulinic acid (LA) and n-hexanol. Parametric studies has been undertaken in order to get maximum LA conversion by varying several reaction parameters such as molar ratio (acid to n-hexanol), catalyst concentration, reaction time, etc. Further catalysts’ reusability studies has been carried out to assess their potential for reusability. The results indicated better catalytic performance of the zeolite H-BEA which is modified with the use of yeast (MBBY) as compared to microporous zeolite H-BEA and MBB catalyst which may be due to its enhanced surface area and surface acidity.

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来源期刊

Catalysis Letters 化学-物理化学

CiteScore

5.70

自引率

3.60%

发文量

327

审稿时长

1 months

期刊介绍： Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis. The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.