Solvent induced self-assembly of dinuclear Eu(III) helicate and emergent strong CPL

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-01-02 DOI:10.1039/d4dt02934h

Xinglu Wang, Qing Ma, Sen Yin, Ting Gao, Pengfei Yan, Yanyan Zhou, Hongfeng Li

引用次数: 0

Abstract

Herein, we report the influence of solvent on the self-assembly of a dinuclear helicate, (NMe4)2[Eu2(LR)4]. A multiple species mixture with the chemical composition of [Eu2(LR)2n]n‒ present in CH₃CN, can be transformed into a helicate upon increasing the content of CHCl₃, accompanied by a significant enhancement in circularly polarized luminescence activity.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.