Solar cells sensitized with doubly concerted companion dyes with optimized donors to achieve high efficiencies up to 12.5%: a record efficiency for iodine electrolyte-based DSSCs†

IF 10.7 2区 材料科学 Q1 CHEMISTRY, PHYSICAL
Zhemin Li, Qingjun Lu, Yuqian Zhang, Qizhao Li, Wenjun Wu, Shijun Li, Hailong Wang, Jianzhuang Jiang, Chengjie Li and Yongshu Xie
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Abstract

Fluorenyl indoline based electron donors have been employed in constructing DSSC dyes with high photocurrents. However, commonly used fluorenyl indoline donors possess two or fewer alkyl chains and thus suffer from serious dye aggregation and charge recombination, resulting in undesirable moderate open-circuit voltages (VOC) in spite of high short-circuit current densities (JSC). To enhance the VOC and maintain high JSC, we herein report the design and synthesis of a fluorenyl indoline donor substituted with a dihexyloxyphenyl moiety, and thus porphyrin dye XW93 and the corresponding doubly concerted companion (DCC) dyes XW94 and XW95 have been synthesized and used to fabricate DSSCs based on iodine electrolyte, achieving enhanced VOC values of 734, 750 and 759 mV, respectively. Meanwhile, XW94 and XW95 exhibit a high IPCE plateau from 370 to 700 nm with onset wavelengths up to 820 nm, affording high JSC values over 22 mA cm−2 and relatively high power conversion efficiencies (PCEs) of 11.8% and 12.1%, respectively. To further improve the VOC, XW96 was synthesized by replacing the fluorenyl indoline donor with a bulky phenothiazine donor. The resulting DSSCs afford a considerably elevated VOC of 782 mV with the JSC slightly lowered to 21.97 mA cm−2. As a result of the excellent VOC and satisfactory JSC, the highest PCE of 12.5% has been achieved for XW96, which is the record efficiency for iodine electrolyte-based DSSCs, to the best of our knowledge. This work provides an effective approach for constructing high-performance DCC dyes based on optimized donors by combining the respective advantages of indoline and phenothiazine donors.

Abstract Image

太阳能电池通过双重协调的伴侣染料与优化供体敏化,实现高达12.5%的高效率:碘电解质基DSSCs的记录
基于氟芴酰吲哚的电子给体被用于构建具有高光电流的DSSC染料。然而,常用的氟酰吲哚给体具有两个或更少的烷基链,因此受到严重的染料聚集和电荷重组的影响,尽管短路电流密度(JSC)很高,但却导致不理想的中等开路电压(VOC)。为了提高挥发性有机化合物(VOC)和保持较高的JSC,我们设计合成了一种取代二己氧基苯基部分的氟芴基吲哚给体,从而合成了卟啉染料XW93和相应的双协同伴侣(DCC)染料XW94 × XW95,并在碘电解质的基础上制备了DSSCs,分别提高了734、750和759 mV的VOC值。同时,XW94和XW95在370 ~ 700 nm范围内表现出较高的IPCE平台,起始波长达到820 nm, JSC值超过22 mA·cm−2,功率转换效率(pce)相对较高,分别为11.8%和12.1%。为了进一步提高VOC,用大体积吩噻嗪取代氟酰吲哚给体合成了XW96。结果表明,DSSCs的VOC显著升高,达到782 mV,而JSC略微降低至21.97 mA·cm−2。由于优异的VOC和令人满意的JSC, XW96的PCE最高达到12.5%,据我们所知,这是碘电解质基DSSCs的最高效率记录。本研究结合吲哚啉和吩噻嗪给体各自的优势,为优化给体构建高性能DCC染料提供了有效途径。
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来源期刊
Journal of Materials Chemistry A
Journal of Materials Chemistry A CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
19.50
自引率
5.00%
发文量
1892
审稿时长
1.5 months
期刊介绍: The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.
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