Tailored Functionalization of Plasmonic AgNPs/C:H:N:O Nanocomposite for Sensitive and Selective Detection.

Sanjay Kumar, Hana Maskova, Anna Kuzminova, Paval Curda, Lenka Doudova, Jan Sterba, Ondřej Kylián, Ryan O M Rego, Vítězslav Straňák
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Abstract

We report here on the development of tailored plasmonic AgNPs/C:H:N:O plasma polymer nanocomposites for the detection of the pathogenic bacterium Borrelia afzelii, with high selectivity and sensitivity. Silver (Ag) nanoparticles, generated by a gas aggregation source, are incorporated onto a C:H:N:O plasma polymer matrix, which is deposited by magnetron sputtering of a nylon 6.6. These anchored Ag nanoparticles propagate localized surface plasmon resonance (LSPR), optically responding to changes caused by immobilized pathogens near the nanoparticles. The tailored functionalization of AgNPs/C:H:N:O nanocomposite surface allows both high selectivity for the pathogen and high sensitivity with an LSPR red-shift Δλ > (4.20 ± 0.71) nm for 50 Borrelia per area 0.785 cm2. The results confirmed the ability of LSPR modulation for the rapid and early detection of (not only) tested pathogens.

等离子体AgNPs/C:H:N:O纳米复合材料的定制功能化敏感和选择性检测。
本文报道了一种具有高选择性和高灵敏度的等离子体AgNPs/C:H:N:O等离子体聚合物纳米复合材料用于检测致病菌伯氏疏螺旋体。银(Ag)纳米颗粒由气体聚集源产生,并结合到C:H:N:O等离子体聚合物基体上,该基体由尼龙6.6磁控溅射沉积。这些锚定的银纳米颗粒传播局部表面等离子体共振(LSPR),光学响应由纳米颗粒附近固定的病原体引起的变化。AgNPs/C:H:N:O纳米复合表面的定制功能化使得病原体具有高选择性和高灵敏度,LSPR红移Δλ bb0(4.20±0.71)nm / 0.785 cm2。结果证实了LSPR调节对(不仅仅是)被测病原体的快速和早期检测的能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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