Hydrothermally Constructed MoS2/ZnIn2S4 Heterostructure for Promotion of Photocatalytic H2 Evolution

IF 3.5 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yu Yang Tang, Yang Fan Yu, Yang Zhang, Peng Fei Liu, Hua Gui Yang
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Abstract

The integration of the second material with unique properties into original material to fabricate heterostructure represents an effective strategy to enhance photocatalytic H2 evolution. Herein, we synthesized a MoS2/ZnIn2S4 heterostructured photocatalyst using a two-step hydrothermal method. The resulting MoS2/ZnIn2S4 displayed the flower-like morphology formed by staked nanosheets, significantly accelerating photocatalytic H2 evolution performance. The optimal MoS2/ZnIn2S4 (ZIS/Mo-50) achieved remarkable photocatalytic H2 production rate of 20.5 mmol g−1 h−1, which is 18.5 times higher than that of pristine ZnIn2S4. Further characterizations proved that the formation of the MoS2/ZnIn2S4 heterostructure adjusted the energy band structure of ZnIn2S4, enhancing its light absorption capability. Additionally, the heterostructure facilitated efficient charge separation and transfer. These enhancements notably boosted the photocatalytic H2 evolution, providing a promising example for designing efficient photocatalysts for H2 evolution.

Abstract Image

水热构建MoS2/ZnIn2S4异质结构促进光催化析氢。
将具有独特性质的第二种材料整合到原始材料中制备异质结构是增强光催化析氢的有效策略。本文采用两步水热法合成了MoS2/ZnIn2S4异质结构光催化剂。得到的MoS2/ZnIn2S4呈现出由片状纳米片形成的花状形貌,显著加快了光催化析氢性能。最优的MoS2/ZnIn2S4 (ZIS/Mo-50)光催化制氢速率为20.5 mmol·g-1·h-1,是原始ZnIn2S4的18.5倍。进一步表征证明,MoS2/ZnIn2S4异质结构的形成调整了ZnIn2S4的能带结构,增强了ZnIn2S4的光吸收能力。此外,异质结构有利于有效的电荷分离和转移。这些改进显著地促进了光催化氢的生成,为设计高效的光催化氢的生成提供了一个有希望的例子。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Chemistry - An Asian Journal
Chemistry - An Asian Journal 化学-化学综合
CiteScore
7.00
自引率
2.40%
发文量
535
审稿时长
1.3 months
期刊介绍: Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
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