{"title":"Employing mesoporous nitrogen containing carbon for simultaneous electrochemical detection of heavy metal ions.","authors":"Naresh Bhatia, Daisy Mehta, Kalpana Garg, Sukhjot Kaur, Tharamani C Nagaiah","doi":"10.1002/asia.202401315","DOIUrl":null,"url":null,"abstract":"<p><p>Heavy metal ions are major contributors to water pollution, posing significant threats to both ecological balance and human health due to their carcinogenic properties. The increasing need for heavy metal detection highlights the advantages of electrochemical methods, which offer high sensitivity and efficiency. Herein mesoporous nitrogen containing carbon (MNC) was utilized for the simultaneous determination of heavy metals using square wave voltammetry technique in the established conditions of a buffer pH of 5.0. MNC demonstrated low detection limits (1, 10 and 50 μM), wide linear ranges (1 μM - 6 mM, 10 μM - 7 mM and 50 μM - 17 mM), and high sensitivities (2.5 μA μM-1 cm-2, 1.03 μA μM-1 cm-2 and 5.14 mA mM-1 cm-2) for, Pb²⁺, Cd²⁺ and Cu²⁺, respectively. Moreover, the reproducibility, and selectivity of the sensor was investigated in the presence of K+, Mg2+, Zn2+, Ni2+, and Fe3+ which are the possible interferents present in water.</p>","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401315"},"PeriodicalIF":3.5000,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - An Asian Journal","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1002/asia.202401315","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Heavy metal ions are major contributors to water pollution, posing significant threats to both ecological balance and human health due to their carcinogenic properties. The increasing need for heavy metal detection highlights the advantages of electrochemical methods, which offer high sensitivity and efficiency. Herein mesoporous nitrogen containing carbon (MNC) was utilized for the simultaneous determination of heavy metals using square wave voltammetry technique in the established conditions of a buffer pH of 5.0. MNC demonstrated low detection limits (1, 10 and 50 μM), wide linear ranges (1 μM - 6 mM, 10 μM - 7 mM and 50 μM - 17 mM), and high sensitivities (2.5 μA μM-1 cm-2, 1.03 μA μM-1 cm-2 and 5.14 mA mM-1 cm-2) for, Pb²⁺, Cd²⁺ and Cu²⁺, respectively. Moreover, the reproducibility, and selectivity of the sensor was investigated in the presence of K+, Mg2+, Zn2+, Ni2+, and Fe3+ which are the possible interferents present in water.
期刊介绍:
Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics.
Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews.
A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal.
Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).