Effect of protonation induced distortions on the spectral properties and electronic structure of Octaphenylporphyrins: UV-vis, electrochemical, VT-NMR and ab initio studies.

IF 3.5 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Nivedita Rana, Soni Kumari, Muniappan Sankar
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引用次数: 0

Abstract

The extent of conformational alteration of the porphyrin macrocycle during the course of protonation was observed, both experimentally and theoretically. For synthesized β-substituted octaphenylporphyrin (OPP) ring systems this macrocyclic distortions have been investigated by spectroscopic and computational analysis. Protonation induced nonplanarity in macrocyclic system is experimentally observed in a single step during spectrophotometric titration. The progress of the protonation by TFA was monitored i.e. the addition of proton to the core of the ring was monitored by UV/Vis spectroscopy, which was also determined logβ value. The spectral changes demonstrate the conformational flexibility of these macrocyclic systems correlating with the photophysical properties. The degree of nonplanarity exhibited incremental progress in response to protonation, with a specific order observed: H2TPP < H2OPP < H2OPPBr4 < H2OPPBr3NO2. Furthermore, our study delved into the structural aspects, frontier molecular orbitals and ground state energies of H4P(CF3COO)2 absorption bands computed at the TD-B3LYP/6-31G level of theory, anticipated a red shift in both the Soret and Q0,0 bands. This theoretical prediction aligns seamlessly with the experimental findings from spectrophotometric titrations, providing validation to our computation insights. In summary, this comprehensive study elucidates the extent of conformational changes occurring in β-substituted OPP ring systems upon protonation and deprotonation.

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来源期刊
Chemistry - An Asian Journal
Chemistry - An Asian Journal 化学-化学综合
CiteScore
7.00
自引率
2.40%
发文量
535
审稿时长
1.3 months
期刊介绍: Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
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