Intrinsically Healable and Photoresponsive Electrospun Fabrics: Integrating PVDF-HFP, TPU, and Azobenzene Ionic Liquids

IF 8.3 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Chun-Chi Chang, Lin-Ruei Lee, Sheng Zheng, Tse-Yu Lo, Chia-Wei Chang, Chia-Ti Wu, Tsung-Hung Tsai, Huan-Ru Chen, Yi-Fan Chen, Ming-Hsuan Chang, Jiun-Tai Chen
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引用次数: 0

Abstract

In recent years, the integration of multifunctional properties into electrospun fabrics has garnered significant attention for applications in wearable devices and smart textiles. A major challenge lies in achieving a balance among intermolecular interactions, structural stability, and responsiveness to external stimuli. In this study, we address this challenge by developing intrinsically healable and photoresponsive electrospun fabrics composed of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), thermoplastic polyurethane (TPU), and an azobenzene-based ionic liquid ([AzoC6MIM][TFSI]). The interactions between PVDF-HFP and [AzoC6MIM][TFSI] enable intrinsic self-healing and light-induced responsiveness, while the incorporation of TPU prevents fiber fusion during electrospinning, maintaining structural integrity and porosity. Our results demonstrate that these fabrics can recover up to 97% of their original mechanical properties after self-healing and exhibit reversible changes in electrical conductivity under UV and visible lights. This versatile approach paves the way for the incorporation of high concentrations of functional ionic liquids into electrospun fabrics, enabling the development of multifunctional textiles with potential applications in self-healing wearable devices and advanced sensors.

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来源期刊
ACS Applied Materials & Interfaces
ACS Applied Materials & Interfaces 工程技术-材料科学:综合
CiteScore
16.00
自引率
6.30%
发文量
4978
审稿时长
1.8 months
期刊介绍: ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.
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