Two-dimensional porous porphyrin materials composed of robust tin(IV)-porphyrin linkages for photocatalytic wastewater remediation

IF 3.5 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR
Nirmal Shee, Hee-Joon Kim
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引用次数: 0

Abstract

Porphyrin-based two-dimensional porous materials (SnP-H2TCPP (1), SnP-ZnTCPP (2)) composed of robust Sn(IV)-porphyrin linkages have been synthesized by reacting trans-dihydroxo[5,10,15,20-tetraphenylporphyrinato]tin(IV) (SnP) with [5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin] (H2TCPP) and [5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato]zinc(II) (ZnTCPP), respectively. The strength of the interaction between the carboxylic acid group of the monomeric porphyrins (H2TCPP and ZnTCPP) and the axial hydroxyl moiety of SnP enables the construction of highly stable framework materials, which were characterized by FT-IR, UV-vis, and emmission spectroscopy, powder XRD, elemental analysis, and thermogravimetric analysis (TGA). 1 and 2 absorb visible light strongly over a wide range, demonstrating weak perturbation in the electronic ground state structures of the π-conjugated aromatic moieties compared to the starting monomeric units. TGA indicated that 1 and 2 exhibited greater thermal stability than SnP. The permanent porosity of 1 and 2 resulted in large specific surface areas (BET) of 210.0 m2g−1 and 185.0 m2g−1, respectively. Uniform spherical nanoplates with an average diameter in the range of 900−1000 nm were observed for 1, whereas a nanocomposite morphology was observed for 2, whose shape and size could not be specifically defined. Finally, the photodegradation performance of 1 and 2 was found to be 89% (K = 0.0179 min−1) and 97% (K = 0.0246 min−1) within 120 min, respectively, for the degradation of methylene blue (MB), and 50% (K = 0.0091 min−1) and 60% (K = 0.0120 min−1) within 75 min, respectively, for the tetracycline (TC) antibiotic. The enhanced catalytic photodegradation activity of 1 or 2 is attributed to the cooperation between the carboxylate-bearing porphyrin units and SnP.
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来源期刊
Dalton Transactions
Dalton Transactions 化学-无机化学与核化学
CiteScore
6.60
自引率
7.50%
发文量
1832
审稿时长
1.5 months
期刊介绍: Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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