Samarium Diiodide/Samarium‐Mediated Deoxygenative Hydroborylation of Aldehydes

IF 2.5 3区化学 Q2 CHEMISTRY, ORGANIC

European Journal of Organic Chemistry Pub Date : 2025-04-01 DOI:10.1002/ejoc.202401249

Prof. Dr. Chengwei Liu , Yilin Ma , Wei Zhou

引用次数: 0

Abstract

A samarium diiodide/samarium‐mediated direct deoxygenative hydroborylation of aldehydes with hydroborate ester has been reported. In this method, unactivated aldehydes and hydroborate ester have been employed as starting materials for the synthesis of primary alkyl borate esters. Broad substrate scope and excellent functional group tolerance have demonstrated that this is a robust method for deoxygenative hydroborylation of aldehydes.

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二碘化钐/钐介导的醛类脱氧氢硼化反应

报道了二碘化钐/钐介导的乙醛与硼酸氢酯直接脱氧硼化反应。该方法以未活化的醛和氢硼酸酯为原料合成伯烷基硼酸酯。广泛的底物范围和良好的官能团耐受性已被证明这是一个强大的方法脱氧硼化醛。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.