Dipin K. Tomar, Swapnil Deshpande, Shubham Gupta, Amogh K. Ravi, Sudip Chakraborty, Pabitra K Nayak, Jyotishman Dasgupta
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引用次数: 0
Abstract
Lower-dimensional organic–inorganic hybrid perovskite materials promise to revolutionize the optoelectronics industry due to the tremendous possibilities of exotic control on excitonic properties driven via quantum confinement. Flexible organic cations acting as spacers and stabilizers enhance electron–phonon couplings, further amplifying the potential for modular light–matter interactions in these materials. Herein we unravel the nature of excitons in a quasi-1D chain of corner-sharing bismuth iodide octahedra with an intrinsic quantum well structure stabilized by a hexyl-diammonium cation. Using broadband femtosecond impulsive Raman spectroscopy and detailed electronic structure calculations, we directly quantify the exciton lifetime along with the electron–phonon coupling constants to fully describe the excitation as an exciton-polaron. We find ∼30 times larger electron–phonon couplings beyond the standard 2D-hybrid perovskite materials along with picosecond time-scale decoherences, thereby shedding light for the first time on the immense potential of these 1D perovskite analogues for developing novel materials for efficient light-conversion technologies.
期刊介绍:
The Journal of Physical Chemistry (JPC) Letters is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, chemical physicists, physicists, material scientists, and engineers. An important criterion for acceptance is that the paper reports a significant scientific advance and/or physical insight such that rapid publication is essential. Two issues of JPC Letters are published each month.