NIR luminescence properties of Nd3+ ion doped glasses medium based on Huta Ginjang quartz sand

IF 2.8 3区物理与天体物理 Q3 CHEMISTRY, PHYSICAL

Radiation Physics and Chemistry Pub Date : 2024-12-04 DOI:10.1016/j.radphyschem.2024.112466

Juniastel Rajagukguk, Pintor Simamora, Ladestam Sitinjak, Elyzabeth Simanullang, C.S. Sarumaha, N. Intachai, S. Kothan, J. kaewkhao

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引用次数: 0

Abstract

Neodymium ions (Nd³⁺) doped into quartz sand and silicate oxide-based glass mediums have been synthesized using the melt-quenching method. The resulting glass samples adhere to the chemical compositions of 5 quartz sand (QS) + 50 B₂O₃ + 10 BaO + 30 Na₂O + 0.5Nd₂O₃ and 5SiO₂ + 50B₂O₃ + 10BaO + 30Na₂O + 0.5Nd₂O₃. These glasses were characterized by density, refractive index, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and absorption spectrum. The quartz sand samples exhibited higher refractive index and molar volume compared to the silica borate samples. XRD spectra revealed the structural properties of the glass samples, while FTIR spectra were recorded across wavelengths from 650 to 4000 cm⁻1. The absorption spectra were observed in the UV–Vis–NIR range from 350 to 1000 nm, revealing 11 transition peaks. Additionally, three emission peaks were identified within the wavelength range of 800–1500 nm, along with the decay time of the glass samples.

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基于呼塔金江石英砂的掺Nd3+玻璃介质的近红外发光性能

钕离子（Nd³）掺杂到石英砂和硅酸盐氧化物基玻璃介质中，采用熔淬法合成。得到的玻璃样品符合5石英砂(QS) + 50B₂O₃+ 10BaO + 30Na₂O + 0.5Nd₂O₃和5SiO₂+ 50B₂O₃+ 10BaO + 30Na₂O + 0.5Nd₂O₃的化学成分。用密度、折射率、x射线衍射（XRD）、傅里叶变换红外光谱（FTIR）和吸收光谱对这些玻璃进行了表征。与硼酸硅样品相比，石英砂样品具有更高的折射率和摩尔体积。XRD光谱显示了玻璃样品的结构特性，而FTIR光谱记录了650至4000 cm⁻1的波长。在350 ~ 1000 nm的紫外-可见-近红外光谱范围内观察到11个过渡峰。在800 ~ 1500 nm的波长范围内发现了3个发射峰，与玻璃样品的衰减时间有关。

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来源期刊

Radiation Physics and Chemistry 化学-核科学技术

CiteScore

5.60

自引率

17.20%

发文量

574

审稿时长

12 weeks

期刊介绍： Radiation Physics and Chemistry is a multidisciplinary journal that provides a medium for publication of substantial and original papers, reviews, and short communications which focus on research and developments involving ionizing radiation in radiation physics, radiation chemistry and radiation processing. The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. This could include papers that are very similar to previous publications, only with changed target substrates, employed materials, analyzed sites and experimental methods, report results without presenting new insights and/or hypothesis testing, or do not focus on the radiation effects.