Isotopic characteristics of antifouling paints and fractionation of Cu and Zn isotopes during dissolution by seawater and their adsorption to marine sediments.

IF 5.3 3区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES
Seokyoon Jang, Mansik Choi, Youn-Joong Jeong, Dongjin Joe, Dasom Yang, Minjae Lee, Jinwoo Kim
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引用次数: 0

Abstract

The elemental and isotopic (δ65Cu and δ66Zn) characteristics of 34 AFP samples from 5 paint manufacturers, the isotopic fractionation during the dissolution of AFPs by seawater, and the subsequent adsorption of isotopes onto coastal fine-grained sediments were investigated to identify potential indicators (metal ratios and isotopes). The δ65Cu and δ66Zn values for 34 AFPs could be divided into 2 groups regardless of the type of paint or manufacturer. Dissolution by seawater induced substantial fractionation but δ65Cu and δ66Zn approached the bulk AFP values when the leached fraction increased. The adsorption of metals onto marine sediments resulted in substantial fractionation (Δ65Cusoln-solid = 0.91 ± 0.30 ‰ and Δ66Zn = -0.14 ± 0.07 ‰), but the δ65Cu values in sediments were similar to those in bulk AFP because almost all of the Cu adsorbed to marine sediments within 12 h.

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来源期刊
Marine pollution bulletin
Marine pollution bulletin 环境科学-海洋与淡水生物学
CiteScore
10.20
自引率
15.50%
发文量
1077
审稿时长
68 days
期刊介绍: Marine Pollution Bulletin is concerned with the rational use of maritime and marine resources in estuaries, the seas and oceans, as well as with documenting marine pollution and introducing new forms of measurement and analysis. A wide range of topics are discussed as news, comment, reviews and research reports, not only on effluent disposal and pollution control, but also on the management, economic aspects and protection of the marine environment in general.
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