Stretchable and self-healing carboxymethyl cellulose/polyacrylic acid conductive hydrogels for monitoring human motions and electrophysiological signals.

IF 7.7 1区 化学 Q1 BIOCHEMISTRY & MOLECULAR BIOLOGY
Xiong Liu, Lizhi Chen, Ayixianguli Sufu, Fangfei Liu
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引用次数: 0

Abstract

Stretchable conductive hydrogels have attracted great attention in flexible electronics. Nevertheless, conductive hydrogels would suffer from an inevitable damage during use, significantly reducing the reliability and limiting the practicability. Herein, stretchable and self-healing conductive hydrogels are designed form carboxymethyl cellulose (CMC), polyacrylic acid (PAA), and Fe3+, which are applied for monitoring human motions and electrophysiological signals. The plentiful H-bonding and metal coordination endow the conductive hydrogels with good mechanical (fracture strain: 917 %; fracture stress: 202 kPa; toughness: 1.1 MJ m-3) and self-healing properties. After self-healing, the fracture stress is almost fully recovered, the fracture strain is restored to 72 %, and the conductivity is reestablished to 98 %. The conductive hydrogels show good fatigue resistance during cyclic tensile and compressive loading-unloading tests. Furthermore, the mechanical deformation would lead to the resistance change of the hydrogel to realize the electrical signal record. So, the hydrogel was assembled into a flexible wearable sensor that has good electrical conductivity (0.779 S m-1), fast responsiveness (response time: 300 ms; recovery time: 200 ms) and high sensitivity (gauge factor (GF) = 7.99, 400-650 %). This work demonstrates a simple and efficient strategy for developing stretchable and self-healing conductive hydrogels in healthcare monitoring and flexible electronics.

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来源期刊
International Journal of Biological Macromolecules
International Journal of Biological Macromolecules 生物-生化与分子生物学
CiteScore
13.70
自引率
9.80%
发文量
2728
审稿时长
64 days
期刊介绍: The International Journal of Biological Macromolecules is a well-established international journal dedicated to research on the chemical and biological aspects of natural macromolecules. Focusing on proteins, macromolecular carbohydrates, glycoproteins, proteoglycans, lignins, biological poly-acids, and nucleic acids, the journal presents the latest findings in molecular structure, properties, biological activities, interactions, modifications, and functional properties. Papers must offer new and novel insights, encompassing related model systems, structural conformational studies, theoretical developments, and analytical techniques. Each paper is required to primarily focus on at least one named biological macromolecule, reflected in the title, abstract, and text.
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