Engineering of lattice defects in supported Cu-Mn-Ce composite oxide catalysts through ultra-low Pd doping and plasma treatment for catalytic oxidation of hexane

IF 7.7 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES
Zihao Li , Zewen Chen , Chen Ye , Lixi Gong , Hui Wang , Jie Zhou
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Abstract

Despite the low cost of supported non-precious metal catalysts, their catalytic activity is significantly lower than that of precious metal catalysts in the catalytic oxidation reaction of volatile organic compounds (VOCs). In order to enhance the catalytic activity of supported non-precious metal catalysts, we introduced an ultra-low loading of palladium into the existing catalytic system and employed a plasma preparation process instead of the conventional impregnation method. The approach significantly improves the catalytic activity of the active sites on the catalyst. The results indicate that, compared to the supported Pd and CuMnCeOx catalysts prepared by conventional impregnation method, the Pd/CuMnCeOx/SiO2-P catalysts prepared via plasma exhibit a higher proportion of lattice defects (oxygen vacancies). Furthermore, the doping of the ultra-low Pd could facilitate the formation of additional lattice defects in the composite oxide. As a result, it can improve the content of surface active oxygen and enhance the adsorptive strength of hexane on the surface of the catalyst. The Pd/CuMnCeOx/SiO2-P catalysts exhibit high catalytic activity and stability in the catalytic oxidation of n-hexane. This work promotes the potential application in the preparation of catalyst with ultra-low precious metal loading.

Abstract Image

通过超低钯掺杂和等离子体处理来设计负载型Cu-Mn-Ce复合氧化物催化剂的晶格缺陷。
负载型非贵金属催化剂虽然成本较低,但在挥发性有机物(VOCs)的催化氧化反应中,其催化活性明显低于贵金属催化剂。为了提高负载型非贵金属催化剂的催化活性,我们在现有的催化体系中引入了超低负载钯,并采用等离子体制备工艺代替传统的浸渍法。该方法显著提高了催化剂上活性位点的催化活性。结果表明,与传统浸渍法制备的负载Pd和CuMnCeOx催化剂相比,等离子体法制备的Pd/CuMnCeOx/SiO2-P催化剂具有更高的晶格缺陷(氧空位)比例。此外,超低Pd的掺杂还可以促进复合氧化物中额外晶格缺陷的形成。因此,它可以提高表面活性氧的含量,增强己烷在催化剂表面的吸附强度。Pd/CuMnCeOx/SiO2-P催化剂对正己烷的催化氧化表现出较高的催化活性和稳定性。本研究在制备超低贵金属负载催化剂方面具有潜在的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Environmental Research
Environmental Research 环境科学-公共卫生、环境卫生与职业卫生
CiteScore
12.60
自引率
8.40%
发文量
2480
审稿时长
4.7 months
期刊介绍: The Environmental Research journal presents a broad range of interdisciplinary research, focused on addressing worldwide environmental concerns and featuring innovative findings. Our publication strives to explore relevant anthropogenic issues across various environmental sectors, showcasing practical applications in real-life settings.
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阿拉丁
Mn(NO3)2 solution
阿拉丁
Cu(NO3)2·3H2O
阿拉丁
Ce(NO3)2·6H2O
阿拉丁
Mn(NO3)2 solution
阿拉丁
Cu(NO3)2·3H2O
阿拉丁
Ce(NO3)2·6H2O
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