Research Progress in Dielectric Properties of Inorganic Two-Dimensional Nano-Fillers Polyvinylidene Fluoride Nano-Dielectric Materials

IF 3.6 4区 工程技术 Q3 ENERGY & FUELS
Jinqi Qin, Hongwei Lu, Shijia Yang, Weitao Su, Yu Xing
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引用次数: 0

Abstract

Two-dimensional (2D) nanofillers can effectively improve the performance of nano-dielectrics by having larger aspect ratios and larger electron-scattering interfaces than one-dimensional (1D) nanofillers and zero-dimensional (0D) nanofillers; the formation of a large interfacial area in the polymer matrix effectively traps or scatters the mobile charges and increases the curvature of the propagation paths of the electric tree, thus effectively increasing the breakdown strength and the energy-storage density of nanodielectrics. In this article, the intrinsic mechanism of 2D nanodielectrics is elaborated using percolation theory, microcapacitance theory, interfacial model, and ping-pong racket model. Surface modification, oriented alignment, and multilayer structural design are reviewed to enhance the dielectric properties of nanodielectrics. Additionally, an outlook on the multiple challenges and potential opportunities in the process of preparing energy-storage capacitors with excellent performance is provided.

无机二维纳米填料聚偏氟乙烯纳米介电材料的介电性能研究进展
与一维(1D)纳米填料和零维(0D)纳米填料相比,二维(2D)纳米填料具有更大的长径比和更大的电子散射界面,可以有效提高纳米电介质的性能;在聚合物基体中形成大的界面区,可以有效地捕获或散射移动电荷,增加电树传播路径的曲率,从而有效提高纳米电介质的击穿强度和储能密度。本文利用渗流理论、微电容理论、界面模型和乒乓球拍模型阐述了二维纳米电介质的内在机理。文章还综述了表面改性、定向排列和多层结构设计等提高纳米电介质介电性能的方法。此外,还展望了制备性能卓越的储能电容器过程中面临的多重挑战和潜在机遇。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Energy technology
Energy technology ENERGY & FUELS-
CiteScore
7.00
自引率
5.30%
发文量
0
审稿时长
1.3 months
期刊介绍: Energy Technology provides a forum for researchers and engineers from all relevant disciplines concerned with the generation, conversion, storage, and distribution of energy. This new journal shall publish articles covering all technical aspects of energy process engineering from different perspectives, e.g., new concepts of energy generation and conversion; design, operation, control, and optimization of processes for energy generation (e.g., carbon capture) and conversion of energy carriers; improvement of existing processes; combination of single components to systems for energy generation; design of systems for energy storage; production processes of fuels, e.g., hydrogen, electricity, petroleum, biobased fuels; concepts and design of devices for energy distribution.
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