A reappraisal of the petrogenesis of Apollo 17 lunar dunites 72415-72417: Relics of the deep lunar mantle?

Abstract

Lunar dunite samples 72415–72417, collected by Apollo 17 astronauts from a South Massif boulder in the Taurus–Littrow valley, are crushed breccias composed of several types of olivine- and clinopyroxene-rich clasts, some of which are (or contain) intergrowths of Cr-spinel and pyroxenes or plagioclase. Among the clasts are ellipsoidal symplectites of Cr-spinel and pyroxene, up to 300 μm in diameter, which have bulk compositions consistent with those of olivine + garnet. These symplectites are inferred to originally have been olivine + Mg-Cr-rich garnet (pyrope–uvarovite) that formed deep in the lunar mantle and were subsequently transported closer to the lunar surface (spinel- or plagioclase-peridotite stability fields), perhaps during gravitationally driven overturn. Abundant microsymplectite (30 μm diameter) intergrowths of Cr-spinel and pyroxene inside olivine grains, many associated with inclusions of plagioclase and augite, formed during a later decompression event (perhaps excavation to the lunar surface). These inclusions have not previously been recorded in these samples and could be responsible for earlier reports of igneous zoning in olivine. Electron backscatter diffraction data show evidence of high shock pressures (>50 GPa), which are inferred to have occurred during the impact which excavated the dunites from the shallow anorthite-bearing lunar mantle. Apatite veinlets post-date the shock metamorphism and have been dated to 3983 ± 72 Ma and 3913 ± 118 Ma by the U–Pb method. This age is consistent with that inferred for the Imbrium impact basin, suggesting that the dunite was finally excavated from the mantle during formation of the Imbrium basin.