Yaqi Ge, Pengfei Diao, Xiangxu Li, Yukun Zhou, Zhenchun Xu, Huiguang Bian, Yao Xiao, Chuansheng Wang
{"title":"Application of DPG/KH550 modified pyrolysis carbon black in oil and high temperature-resistant NBR composites","authors":"Yaqi Ge, Pengfei Diao, Xiangxu Li, Yukun Zhou, Zhenchun Xu, Huiguang Bian, Yao Xiao, Chuansheng Wang","doi":"10.1002/app.56377","DOIUrl":null,"url":null,"abstract":"<p>In this paper, pyrolysis carbon black (CBp) was introduced into nitrile butadiene rubber (NBR), the effects of the ratio of CBp and carbon black (N326) on the properties of NBR composites were investigated, and the optimal ratio was determined. On this basis, the accelerator DPG, coupling agent KH550 and CBp were modified by ball milling and plasma. The results showed that when the ratio of CBp to N326 was 40:15, the overall properties of NBR composites was better. Compared with the unmodified CBp/NBR composites, the change rate of tensile product, resilience and DIN abrasion of ball milling-plasma modified CBp/NBR composites in oil environment were reduced by 52.96%, 12.81%, and 27.19%, respectively, and the tear strength after double damage by high temperature and oil bath was increased by 15.63%, which resulted in better oil and high temperature-resistance. In summary, the ball milling-plasma combined with DPG/KH550 modified CBp can not only replace N326 carbon black, but also realize the preparation of NBR composites with better oil and high temperature-resistance.</p>","PeriodicalId":183,"journal":{"name":"Journal of Applied Polymer Science","volume":"142 3","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/app.56377","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
In this paper, pyrolysis carbon black (CBp) was introduced into nitrile butadiene rubber (NBR), the effects of the ratio of CBp and carbon black (N326) on the properties of NBR composites were investigated, and the optimal ratio was determined. On this basis, the accelerator DPG, coupling agent KH550 and CBp were modified by ball milling and plasma. The results showed that when the ratio of CBp to N326 was 40:15, the overall properties of NBR composites was better. Compared with the unmodified CBp/NBR composites, the change rate of tensile product, resilience and DIN abrasion of ball milling-plasma modified CBp/NBR composites in oil environment were reduced by 52.96%, 12.81%, and 27.19%, respectively, and the tear strength after double damage by high temperature and oil bath was increased by 15.63%, which resulted in better oil and high temperature-resistance. In summary, the ball milling-plasma combined with DPG/KH550 modified CBp can not only replace N326 carbon black, but also realize the preparation of NBR composites with better oil and high temperature-resistance.
期刊介绍:
The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.