Microscopic mineralogy of zoned pyroxene in NWA 12522: Implications for the crystallization histories of the shergottites

IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS
Zhuang Guo, Yu Zhu, Yang Li, Ian M. Coulson, Xiongyao Li, Jianzhong Liu
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Abstract

Basaltic shergottites are the most abundant rock type of Martian meteorites, and pyroxene grains within shergottites commonly show a zoned structure. Here, the detailed microscopic mineralogical characteristics of patchy zoned pyroxene in basaltic shergottite NWA 12522 were investigated by a combination of scanning electron microscopy, electron microprobe, Raman spectroscopy, and transmission electron microscopy. The results show that the cores of zoned pyroxene in NWA 12522 have a homogeneous Mg# value and consist mainly of augite and pigeonite. By contrast, the rim of zoned pyroxene is extremely ferroan and can be further divided into two regions based on quite distinct mineralogy and textures (i.e., far-core and near-core pyroxene rims). The near-core rim shows narrow exsolution lamellae (~35 nm) that were cross-cut by thin pigeonite veinlets and contain abundant nano-sized particles of metastable pyroxferroite and pigeonite. Only relatively coarse exsolution lamellae (~80 nm) were observed in the far-core pyroxene rim regions. The distinct mineralogical characteristics of the pyroxene rims and cores in NWA 12522 imply different crystallization conditions, and the homogeneous Mg-rich pyroxene cores should have slowly crystallized from magma within a deep-seated chamber, followed by an overgrown evolved melt on these pyroxene cores during their ascent to the Martian surface, and disequilibrium crystallization of nano-sized metastable phase (pyroxferroite) occurred in the near-core region. The abnormally low ΣREE contents and steep REE pattern (high Yb/La ratio) of the pyroxene rims in NWA 12522 imply that merrillite should have crystallized prior to the pyroxene rims, making the residual melt become REE-depleted and HREE-enriched.

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来源期刊
Meteoritics & Planetary Science
Meteoritics & Planetary Science 地学天文-地球化学与地球物理
CiteScore
3.90
自引率
31.80%
发文量
121
审稿时长
3 months
期刊介绍: First issued in 1953, the journal publishes research articles describing the latest results of new studies, invited reviews of major topics in planetary science, editorials on issues of current interest in the field, and book reviews. The publications are original, not considered for publication elsewhere, and undergo peer-review. The topics include the origin and history of the solar system, planets and natural satellites, interplanetary dust and interstellar medium, lunar samples, meteors, and meteorites, asteroids, comets, craters, and tektites. Our authors and editors are professional scientists representing numerous disciplines, including astronomy, astrophysics, physics, geophysics, chemistry, isotope geochemistry, mineralogy, earth science, geology, and biology. MAPS has subscribers in over 40 countries. Fifty percent of MAPS'' readers are based outside the USA. The journal is available in hard copy and online.
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