Thermochromic insulation composites for prewarning of thermal faults in electrical equipment

IF 2.7 3区 化学 Q2 POLYMER SCIENCE
Xianrui Jiang, Tianyu Hu, Ke Yao, Ruotong Xiong, Jiashu Qu, Qichang Liu, Chaolu Niu, Potao Sun, Wenxia Sima
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Abstract

Thermal faults occur in the continuous operation of electrical equipment. This poses a threat to the stable operation of power systems. However, existing detection methods do not apply to large-scale temperature measurement scenarios due to high cost and poor stability. To solve the above problems, a reversible thermochromic microcapsule is proposed in this work. Silicone rubber composite can be endowed with thermal sensing capability by doping an appropriate amount of thermochromic microcapsules inside the silicone rubber matrix. The test results showed that the color of the obtained thermochromic composites changed sensitively with the change in external temperature. The material undergoes a sudden color change at about 50°C achieving a reversible color change from blue to colorless. The color difference before and after the color change can be up to 37.24. In addition, the color difference shows an exponential decay trend with time. When the dopant concentration of the microcapsules is 1.5 wt%, the composite material shows excellent color-changing performance, and the insulation strength is increased by 6.92% compared with the pure silicone rubber. Meanwhile, the water contact angle of the composite is 115.3°, which proves that it has good hydrophobicity. Notably, the thermochromic composite also showed excellent weathering properties in thermal aging experiments. The thermochromic microcapsule proposed in this work can realize the visualization of the local overheating state of the electrical equipment, which provides a new idea for the application of thermal fault prewarning of the electrical equipment.

Abstract Image

电气设备热故障预警用热致变色绝缘复合材料
电气设备在连续运行过程中发生热故障。这对电力系统的稳定运行构成了威胁。然而,现有的检测方法成本高,稳定性差,不适合大规模的温度测量场景。为了解决上述问题,本文提出了一种可逆的热致变色微胶囊。通过在硅橡胶基体中掺入适量的热致变色微胶囊,可以使硅橡胶复合材料具有热感能。实验结果表明,所制得的热致变色复合材料的颜色随外界温度的变化而发生敏感的变化。该材料在约50°C时经历突然的颜色变化,实现从蓝色到无色的可逆颜色变化。变色前后的色差可达37.24。色差随时间呈指数衰减趋势。当微胶囊的掺杂浓度为1.5 wt%时,复合材料表现出优异的变色性能,绝缘强度较纯硅橡胶提高6.92%。同时,复合材料的水接触角为115.3°,证明其具有良好的疏水性。值得注意的是,热致变色复合材料在热老化实验中也表现出优异的耐候性能。本文提出的热致变色微胶囊可以实现电气设备局部过热状态的可视化,为电气设备热故障预警的应用提供了新的思路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
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