Lithium Kinetics in Ag–C Porous Interlayer in Reservoir-Free Solid-State Batteries

IF 24.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Se Hwan Park, Kaustubh G. Naik, Bairav S. Vishnugopi, Partha P. Mukherjee, Kelsey B. Hatzell
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引用次数: 0

Abstract

Lithium reservoir-free solid-state batteries (SSBs) can potentially be energy-dense alternatives to conventional lithium-ion batteries. However, controlling the morphology and organization of lithium metal at a current collector remains a challenge and hampers the cycle lifetime of these types of batteries. Porous interlayers have the potential to guide uniform lithium plating and improve electrochemical performance. Factors such as stack pressure, interlayer composition, current density, and interlayer mechanical properties all influence lithium electrode kinetics. This study explores how these kinetic factors impact lithium movement through a porous silver–carbon (Ag-C) interlayer, lithium electrodeposits morphology, and electrochemical performance. Silver nanoparticles in interlayer can facilitate the lithium movement and induce internal stress which contributes to void formation which impedes the lithium flow. Decreasing pore sizes in the interlayer can lead to creep enhancement and preferential formation of lithium metal at the current collector. Porosity-driven creep enhancement is correlated with the formation of denser and uniform electrodes which enable greater reversible operation at lower pressures.

Abstract Image

无储层固态电池Ag-C多孔夹层中锂动力学研究
无锂储层固态电池(SSB)有可能成为传统锂离子电池的高能量替代品。然而,在集流器上控制锂金属的形态和组织仍然是一项挑战,并妨碍了这类电池的循环寿命。多孔夹层具有引导均匀镀锂和改善电化学性能的潜力。叠层压力、夹层成分、电流密度和夹层机械性能等因素都会影响锂电极动力学。本研究探讨了这些动力学因素如何影响锂在多孔银碳(Ag-C)夹层中的移动、锂电沉积物形态以及电化学性能。夹层中的纳米银粒子可促进锂的移动,并产生内应力,从而形成空隙,阻碍锂的流动。夹层中孔隙尺寸的减小会导致蠕变增强,并在电流收集器处优先形成金属锂。孔隙驱动的蠕变增强与更致密、更均匀的电极的形成有关,这种电极能够在更低的压力下进行更大程度的可逆操作。
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来源期刊
Advanced Energy Materials
Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
41.90
自引率
4.00%
发文量
889
审稿时长
1.4 months
期刊介绍: Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.
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