K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family

IF 4.3 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR
Wencong Li, Zhaowei Hu, Yanyan Ding, Yueting Zhu, Qun Jing, Lili Liu
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Abstract

The discovery and synthesis of new NLO materials in the ultraviolet (UV) region are crucial to developing laser technology. The chemical substitution strategy is an effective pathway to design potential UV or DUV NLO crystals. Herein, two new compounds, K6NaCaY2(B5O10)3 and K6NaCaLu2(B5O10)3, have been synthesized using KB5O8·4H2O as the template. Their crystal structures feature a three-dimensional (3D) [Re2(B5O10)3] framework consisting of [B5O10] groups and [ReO6] octahedra, and the remainder of metal cations fill the void to control charge balance and maintain the stability of the crystal structure. Both K6NaCaY2(B5O10)3 and K6NaCaLu2(B5O10)3 crystallize in the acentric space group R32, so they exhibit an SHG effect, and the value is ∼0.5 × KDP (KH2PO4). Meanwhile, they show a phase-matching ability. Due to the participation of alkali metals, alkaline earth metal, and [B5O10] unit, the title compounds possess short absorption edges of ∼230 nm. In addition, they have high thermal stability and can be stable up to 931 °C. These results confirm the effectiveness of the chemical substitution strategy for designing NLO compounds, and then the two compounds can potentially serve as good UV NLO materials.

Abstract Image

K6NaCaRe2(B5O10)3 (Re = Y, Lu): A7-xA 'xAeRe2 (B5O10)3 (x = 0,1)族中具有短吸收边的两种NLO化合物
在紫外区发现和合成新的NLO材料对激光技术的发展至关重要。化学取代策略是设计潜在UV或DUV NLO晶体的有效途径。本文以KB5O8·4H2O为模板,合成了两个新化合物K6NaCaY2(B5O10)3和K6NaCaLu2(B5O10)3。它们的晶体结构具有由[B5O10]基团和[ReO6]八面体组成的三维(3D) [Re2(B5O10)3]∞框架,剩余的金属阳离子填充空隙,控制电荷平衡,保持晶体结构的稳定性。K6NaCaY2(B5O10)3和K6NaCaLu2(B5O10)3均在非中心空间群R32中结晶,表现出SHG效应,其值为~ 0.5 × KDP (KH2PO4)。同时,它们具有相位匹配能力。由于碱金属、碱土金属和[B5O10]单元的参与,标题化合物具有约230 nm的短吸收边。此外,它们具有很高的热稳定性,可以稳定到931°C。这些结果证实了化学取代策略在设计NLO化合物方面的有效性,然后这两种化合物有可能成为良好的UV NLO材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Inorganic Chemistry
Inorganic Chemistry 化学-无机化学与核化学
CiteScore
7.60
自引率
13.00%
发文量
1960
审稿时长
1.9 months
期刊介绍: Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.
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