Flotation enhancement of spodumene with a β-amino-hydroxamate surfactants

Abstract

In view of the combination of dodecylamine and hydroxamate can improve the flotation recovery of spodumene, a novel β-amino-hydroxamate surfactant, i.e., N-(3-(dodecylamino)) hydroxamic acid (DAHA), was designed and introduced into spodumene flotation. The micro-flotation performance indicated that DAHA performed excellent collecting ability toward spodumene, and 2.0 × 10^-4 mol/L of DAHA floated out about 90.2 % of spodumene, while that of sodium oleate (NaOL) was only about 57.4 %. The zeta potential of DAHA-treated spodumene revealed the effective chemisorption of hydroxamate group on spodumene surface. FTIR and XPS recommended that the hydroxamate group in DAHA chelated with surface Al sites to form five-membered hydroxamate-(O,O)-Al complexes. The affinity of DAHA on spodumene spontaneously enhanced by the protonated amino group (–NH₃⁺), which facilitated the chelation of hydroxamate with the surface Al atoms and strengthened the hydrophobicity of spodumene.