Mechanically Resilient, Self-Healing, and Environmentally Adaptable Eutectogel-Based Triboelectric Nanogenerators for All-Weather Energy Harvesting and Human–Machine Interaction
Shaochao Sun, Sanwei Hao, Yongquan Liu, Shaofei Sun, Ying Xu, Ming Jiang, Changyou Shao, Jialong Wen, Runcang Sun
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引用次数: 0
Abstract
Triboelectric nanogenerators (TENGs) have garnered significant attention for mechanical energy harvesting, self-powered sensing, and human–machine interaction. However, their performance is often constrained by materials that lack sufficient mechanical robustness, self-healing capability, and adaptability to environmental extremes. Eutectogels, with their inherent ionic conductivity, thermal stability, and sustainability, offer an appealing alternative as flexible TENG electrodes, yet they typically suffer from weak damage endurance and insufficient self-healing capability. To overcome these challenges, here, we introduce an internal-external dual reinforcement strategy (IEDRS) that enhances internal bonding dynamics within the eutectogel matrix, composed of glycidyl methacrylate and deep eutectic solvent, and integrates plant-derived lignin as an external reinforcer. Notably, the resultant eutectogel, named GLCL, exhibits appealing collection merits including superior mechanical robustness (1.53 MPa tensile stress and 1.85 MJ/m3 toughness), ultrastrong adhesion (4.76 MPa), high self-healing efficiency (84.7%), and significant environmental adaptability (−40 to 100 °C). These improvements ensure that the assembled triboelectric nanogenerator (GLCL-TENG) produces stable and robust electrical outputs, maintained even under dynamic and postdamage conditions. Additionally, the GLCL-TENG exhibits significant extreme environmental tolerance and durability, maintaining high and consistent electrical outputs over a wide temperature range (−40 to 100 °C) and throughout 10,000 cycles of repeated contact-separation. Leveraging these robust performances, the GLCL-TENG excels in all-weather biomechanical energy harvesting and accurate individual motion detection and functions as a self-powered interface for wireless vehicular control. This work presents a viable material design strategy for developing tough and self-healing eutectogel electrodes, emphasizing the potential application of TENGs in all-weather smart vehicles.
期刊介绍:
ACS Nano, published monthly, serves as an international forum for comprehensive articles on nanoscience and nanotechnology research at the intersections of chemistry, biology, materials science, physics, and engineering. The journal fosters communication among scientists in these communities, facilitating collaboration, new research opportunities, and advancements through discoveries. ACS Nano covers synthesis, assembly, characterization, theory, and simulation of nanostructures, nanobiotechnology, nanofabrication, methods and tools for nanoscience and nanotechnology, and self- and directed-assembly. Alongside original research articles, it offers thorough reviews, perspectives on cutting-edge research, and discussions envisioning the future of nanoscience and nanotechnology.