Highly stretchable, self-healing, adhesive, 3D-printable and antibacterial double-network hydrogels for multifunctional wearable sensors.

Abstract

Conductive hydrogels based on sodium alginate (SA) have potential applications in human activity monitoring and personal medical diagnosis due to their good conductivity and flexibility. However, most sensing SA-hydrogels exhibit poor mechanical properties and lack of self-healing, self-adhesive, and antibacterial properties, greatly limiting their practical applications. Therefore, in this paper, a multifunctional double-network PAA-SA hydrogel consisting of poly(acrylic acid) (PAA) and sodium alginate (SA) was prepared by a simple strategy. As a rigid network structure, SA endowed the hydrogel double network structure with excellent mechanical performance. As a wearable sensor, the PAA-SA hydrogel exhibited excellent tensile properties (strain: 1799.2 %), self-healing, high sensitivity (GF = 9.9), reliable repeatability, self-adhesive, 3D printability and antibacterial activity. Additionally, the highly sensitive wearing sensing PAA-SA hydrogel could accurately and real-time monitor various intense or subtle human movements, such as joint bending, face and throat vibration. Moreover, PAA-SA hydrogels were not only used for handwritten recognition of Arabic numerals and English letters, but also for real-time sensing of temperature changes and monitoring of human sweating. The prepared multifunctional wearable sensing hydrogel has the advantages of simple and versatile methods and low cost, making it a promising candidate for applications in different fields such as electronic skin, soft robotics, and medical monitoring.