Evolution from micropinned to polymeric alloy structure of XLPE-PS: Improving electrical properties and mechanism

IF 2.7 3区 化学 Q2 POLYMER SCIENCE
Muneeb Ahmed, Lisheng Zhong, Fei Li, Rui Sui, Ming Wu, Jinghui Gao
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Abstract

This research investigates the transition from a micropinned to a polymeric alloy structure in crosslinked-polyethylene-polystyrene (XLPE-PS). Incorporating 2 wt% 10 μm PS particles into low-density polyethylene (LDPE) and crosslinking with 2 wt% dicumyl peroxide (DCP) forms XLPE-PS structures. The polymeric alloy structure, formed at 220°C extrusion, contrasts with the micropinned formed at 150°C. Morphological, thermo-structural, chemical, and crystal properties are examined to understand their impact on electrical properties and charge transport mechanisms. Results indicate that the polymeric alloy effectively resolves void/crack issues, whereas the micropinned exhibits phase separation. Both structures exhibit a benzene-crosslinked network, and variations in these structures lead to significant changes in thermo-structural, chemical, and crystalline properties. The polymeric alloy XLPE-PS shifts the polyethylene (PE) hkl crystal planes, confirming phase shift and optimal alloying. The structural alterations reveal deeper traps and higher densities in the polymeric alloy XLPE-PS, leading to significantly improved electrical properties, including reduced DC conductivity by up to 1.3 and 0.7 decades at 30 and 90°C, and increased DC breakdown strength by up to 40.34% and 16.17% at 30 and 90°C, respectively, compared with micropinned XLPE-PS. This research offers insights into stable high-voltage insulation development.

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来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
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