Evolution from micropinned to polymeric alloy structure of XLPE-PS: Improving electrical properties and mechanism

IF 2.7 3区 化学 Q2 POLYMER SCIENCE
Muneeb Ahmed, Lisheng Zhong, Fei Li, Rui Sui, Ming Wu, Jinghui Gao
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Abstract

This research investigates the transition from a micropinned to a polymeric alloy structure in crosslinked-polyethylene-polystyrene (XLPE-PS). Incorporating 2 wt% 10 μm PS particles into low-density polyethylene (LDPE) and crosslinking with 2 wt% dicumyl peroxide (DCP) forms XLPE-PS structures. The polymeric alloy structure, formed at 220°C extrusion, contrasts with the micropinned formed at 150°C. Morphological, thermo-structural, chemical, and crystal properties are examined to understand their impact on electrical properties and charge transport mechanisms. Results indicate that the polymeric alloy effectively resolves void/crack issues, whereas the micropinned exhibits phase separation. Both structures exhibit a benzene-crosslinked network, and variations in these structures lead to significant changes in thermo-structural, chemical, and crystalline properties. The polymeric alloy XLPE-PS shifts the polyethylene (PE) hkl crystal planes, confirming phase shift and optimal alloying. The structural alterations reveal deeper traps and higher densities in the polymeric alloy XLPE-PS, leading to significantly improved electrical properties, including reduced DC conductivity by up to 1.3 and 0.7 decades at 30 and 90°C, and increased DC breakdown strength by up to 40.34% and 16.17% at 30 and 90°C, respectively, compared with micropinned XLPE-PS. This research offers insights into stable high-voltage insulation development.

Abstract Image

XLPE-PS从微钉结构到聚合合金结构的演变:电性能的改善及其机理
本文研究了交联聚乙烯-聚苯乙烯(XLPE-PS)从微钉结构到聚合物合金结构的转变。将2 wt% 10 μm PS颗粒掺入低密度聚乙烯(LDPE)中,并与2 wt%过氧化二氨基(DCP)交联,形成XLPE-PS结构。220°C挤压形成的聚合物合金结构与150°C挤压形成的微钉状结构形成对比。形态,热结构,化学和晶体性质进行检查,以了解他们的电学性质和电荷传输机制的影响。结果表明,聚合物合金有效地解决了空洞/裂纹问题,而微钉钉则表现出相分离。这两种结构都表现出苯交联网络,这些结构的变化导致热结构、化学和晶体性质的显著变化。聚合物合金XLPE-PS使聚乙烯(PE) hkl晶面发生位移,证实了相移和最佳合金化。与微细钉钉XLPE-PS相比,聚合物合金XLPE-PS的结构变化显示出更深的陷阱和更高的密度,从而显著改善了电学性能,包括在30和90°C时降低了1.3和0.7倍的直流电导率,在30和90°C时提高了40.34%和16.17%的直流击穿强度。这项研究为稳定的高压绝缘开发提供了见解。
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来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
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