Room-Temperature Deposition of δ-Ni5Ga3 Thin Films and Nanoparticles via Magnetron Sputtering

IF 3.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Filippo Romeggio*, Rasmus Bischoff, Clara B. Møller, Victor L. Jensen, Esteban Gioria, Rikke Egeberg Tankard, Rasmus S. Nielsen, Ole Hansen, Ib Chorkendorff, Jakob Kibsgaard and Christian D. Damsgaard*, 
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引用次数: 0

Abstract

Magnetron sputtering is a versatile method for investigating model system catalysts thanks to its simplicity, reproducibility, and chemical-free synthesis process. It has recently emerged as a promising technique for synthesizing δ-Ni5Ga3 thin films. Physically deposited thin films have significant potential to clarify certain aspects of catalysts by eliminating parameters such as particle size dependence, metal–support interactions, and the presence of surface ligands. In this work, we demonstrate the potential of magnetron sputtering for the synthesis and analysis of thin film catalysts, using Ni5Ga3 as a model system. Initially, deposition conditions were optimized by varying the deposition pressure, followed by an investigation of the temperature effects, aiming to map a structure zone dependence on temperature and pressure as in the Thornton model. The evolution of film crystallinity was monitored using a combination of grazing incidence X-ray diffraction (GI-XRD) and high-resolution scanning electron microscopy (HR-SEM). Additionally, ultrathin films were synthesized and annealed in H2 at high temperatures to demonstrate the possibility of producing size-controlled nanoparticles by adjusting the annealing conditions. This work demonstrates the full potential of magnetron sputtering as a technique for synthesizing model system catalysts in various forms, opening new avenues for the research and development of additional catalytic systems.

磁控溅射室温沉积δ-Ni5Ga3薄膜和纳米颗粒
磁控溅射由于其简单、可重复性和无化学合成过程,是研究模型体系催化剂的一种通用方法。近年来,它已成为合成δ-Ni5Ga3薄膜的一种很有前途的技术。物理沉积的薄膜通过消除诸如粒度依赖性、金属支撑相互作用和表面配体的存在等参数,在澄清催化剂的某些方面具有重要的潜力。在这项工作中,我们以Ni5Ga3为模型体系,展示了磁控溅射在薄膜催化剂的合成和分析中的潜力。首先,通过改变沉积压力来优化沉积条件,然后研究温度效应,旨在绘制与温度和压力相关的结构区域,就像Thornton模型一样。利用掠射x射线衍射(GI-XRD)和高分辨率扫描电镜(HR-SEM)监测了薄膜结晶度的演变。此外,制备了超薄膜并在高温下在H2中退火,以证明通过调整退火条件可以制备尺寸可控的纳米颗粒。这项工作证明了磁控溅射作为一种合成各种形式模型体系催化剂的技术的全部潜力,为研究和开发其他催化体系开辟了新的途径。
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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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