Mg2+/S Co-Decorated V, O Sites to Construct Multi-Defect V2O5 as a Sulfur-Wrapped Matrix for High-Performance Lithium–Sulfur Batteries

IF 5.2 3区 工程技术 Q2 ENERGY & FUELS
Lan Li, Tingxue Fang, Fuming Lai, Xinyue Li, Tingting Qu, Lin Wang, Xiaoshi Lang* and Kedi Cai*, 
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Abstract

Vanadium pentoxide (V2O5) is regarded as a promising sulfur-wrapped matrix for high-performance lithium–sulfur batteries, owing to its desirable structural and functional characteristics. In this paper, a large number of defective sites arise in the vanadium pentoxide structure via a codecoration strategy of the V, O sites, which is more beneficial to improving the electroconductivity and allows for the uniform loading of sulfur on the surface, thereby reducing the polarization resistance and elevating the kinetic rates during the electrochemical reaction. Electrochemical test results indicate that Mg2+/S-codecorated V2O5/S composite cathodes have 1131.15, 942.39, and 804.71 mAh·g–1 of discharge-specific capacities at 0.1, 0.2, and 0.5 C rates, respectively, with the lowest charge/discharge plateau voltage difference, and the capacity retention rate after 140 cycles can be 57.95%. Besides that, the multidefect V2O5 can effectively promote the adsorption strength of lithium polysulfide and catalytically accelerate the rate of liquid-phase conversion between lithium polysulfide so as to achieve the stable electrochemical properties for sulfur composite cathodes.

Abstract Image

Mg2+/S协同修饰V, O位点构建多缺陷V2O5硫包覆矩阵
五氧化二钒(V2O5)由于其良好的结构和功能特性,被认为是一种很有前途的高性能锂硫电池硫包膜材料。在本文中,通过V、O位点的共修饰策略,在五氧化二钒的结构中产生了大量的缺陷位点,这更有利于提高电导率,并允许硫在表面均匀负载,从而降低极化电阻,提高电化学反应的动力学速率。电化学测试结果表明,在0.1、0.2和0.5 C倍率下,Mg2+/S修饰的V2O5/S复合阴极的放电比容量分别为1131.15、942.39和804.71 mAh·g-1,充放电平台电压差最小,140次循环后的容量保持率为57.95%。此外,多缺陷V2O5可以有效提高多硫化锂的吸附强度,催化加速多硫化锂之间的液相转化速率,从而实现硫复合阴极稳定的电化学性能。
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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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阿拉丁
MgCl2·6H2O
阿拉丁
NH4VO3
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