Adsorption Equilibrium, Kinetics, and Column Breakthrough Data of Acetic Acid, Butyric Acid, and Lactic Acid on the IRN-78 Ion-Exchange Resin at Initial pH (∼3–7) and Temperature (25–55 °C)

Abstract

This work presents systematic aqueous-phase adsorption equilibrium, kinetics, and column breakthrough measurements with three key biointermediates that are common compounds in many bioprocesses. Adsorption equilibrium experiments were carried out with acetic acid, butyric acid, and lactic acid on a commercial ion-exchange resin, Amberlite IRN-78, at wide ranges of acid concentration (8–500 mmol/L), initial pH (∼3–7), and temperature (25–55 °C), simulating the effluent characteristics from different fermenter operations. The kinetics and column breakthrough experiments were conducted at an initial pH of 6 and a concentration of 200 mmol/L. The equilibrium study shows a higher loading at the initial pH < pK_a and a lower loading at the initial pH > pK_a. Overall removal varies between 16 and 99% depending on the initial pH, temperature, and organic acid concentration and type. The study further indicates monolayer adsorption at the equilibrium pH > 10 and multilayer adsorption at the equilibrium pH < 6. The thermodynamic modeling of adsorption isotherm data was carried out using Langmuir and Freundlich isotherms. IRN-78 presents fast adsorption kinetics as the maximum loading was attained in ≤10 min and nearly the same breakthrough time for all three organic acids involved in this study.