Nuwayo Eric Munyaneza, Ruiyang Ji, Adrian DiMarco, Joel Miscall, Lisa Stanley, Nicholas Rorrer, Rui Qiao, Guoliang Liu
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引用次数: 0
Abstract
Escalating global plastic pollution and the depletion of fossil-based resources underscore the urgent need for innovative end-of-life plastic management strategies in the context of a circular economy. Thermolysis is capable of upcycling end-of-life plastics to intermediate molecules suitable for downstream conversion to eventually high-value chemicals, but tuning the molar mass distribution of the products is challenging. Here we report a temperature-gradient thermolysis strategy for the conversion of polyethylene and polypropylene into hydrocarbons with tunable molar mass distributions. The whole thermolysis process is catalyst- and hydrogen-free. The thermolysis of polyethylene and polyethylene/polypropylene mixtures with tailored temperature gradients generated oil with an average chain length of ~C14. The oil featured a high concentration of synthetically useful α-olefins. Computational fluid dynamics simulations revealed that regulating the reactor wall temperature was the key to tuning the hydrocarbon distributions. Subsequent oxidation of the obtained α-olefins by sulfuric acid and neutralization by potassium hydroxide afforded sulfate detergents with excellent foaming behaviour and emulsifying capacity and low critical micelle concentration. Overall, this work provides a viable approach to producing value-added chemicals from end-of-life plastics, improving the circularity of the anthropogenic carbon cycle. The controllable conversion of plastic wastes to products with tailored molar mass would facilitate waste valorization but remains challenging. This study presents a catalyst- and hydrogen-free temperature-gradient thermolysis strategy to achieve this goal.
期刊介绍:
Nature Sustainability aims to facilitate cross-disciplinary dialogues and bring together research fields that contribute to understanding how we organize our lives in a finite world and the impacts of our actions.
Nature Sustainability will not only publish fundamental research but also significant investigations into policies and solutions for ensuring human well-being now and in the future.Its ultimate goal is to address the greatest challenges of our time.