Liquid Phase Peroxide Oxidation of Phenol in the Presence of Catalysts Based on Mixed Oxides of Transition Metals and Cellulose

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED
A. A. Perebeinos, T. I. Mishchenko, V. V. Gurovskii, T. B. Medvedeva, D. A. Yatsenko, N.V. Gromov
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Abstract

The work is devoted to the study of the process of water purification from phenol, which was oxidized in the process of liquid-phase peroxide oxidation in the presence of catalysts of composite materials based on MeFe2O4 (Me = Mn, Co, Mg, Cu) and cellulose. The textural and acidic properties of the catalysts were studied. It was shown that the main phase of the catalysts is MeFe2O4, acidity of aqueous suspensions of catalysts are neutral and slightly alkaline. Among the tested catalysts, the CuFe2O4/CMC (microcrystalline cellulose) sample had the greatest efficiency, in the presence of which the phenol conversion was achieved 100% for 20 min of reaction time. Copper and manganese had the greatest effectiveness as Me in the MeFe2O4/CMC system.

Abstract Image

以过渡金属和纤维素的混合氧化物为基础的催化剂存在时苯酚的液相过氧化物氧化作用
本文主要研究了液相过氧化氧化过程中被氧化的苯酚在MeFe2O4 (Me = Mn, Co, Mg, Cu)和纤维素复合材料催化剂作用下的水净化过程。研究了催化剂的结构和酸性。结果表明,催化剂的主相为MeFe2O4,催化剂水悬浮液的酸度为中性和微碱性。在所测试的催化剂中,CuFe2O4/CMC(微晶纤维素)样品的效率最高,在其存在下,反应时间为20 min,苯酚转化率达到100%。在MeFe2O4/CMC体系中,铜和锰作为Me的效果最好。
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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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