Fast and Facile Synthesis of Cobalt-Doped ZIF-8 and Fe3O4/MCC/Cobalt-Doped ZIF-8 for the Photodegradation of Organic Dyes under Visible Light

Abstract

Co-doped ZIF-8 as a water-stable visible light photocatalyst was prepared by using a one-pot, fast, cost-effective, and environmentally friendly method. The band structure of ZIF-8 was tuned through the incorporation of different percentages of cobalt to attain an optimal band gap (E_g) that enables the activation of ZIF-8 under visible light and minimizes the recombination of photogenerated charge carriers. A magnetic composite of Co-doped ZIF-8 was also synthesized to facilitate catalyst recycling and reusability through the application of an external magnetic field. Surface modification of magnetic Fe₃O₄ nanoparticles with microcrystalline cellulose (MCC) was used to reduce the level of agglomeration. The photocatalytic activities of Co-doped ZIF-8 (Co-ZIF-8) and Fe₃O₄/MCC/Co-ZIF-8 were evaluated for the photodegradation of methylene blue (MB) under visible light irradiation from a 20 W LED source. Co-ZIF-8 showed considerably higher photocatalytic activity than pure ZIF-8, confirming the success of the doping strategy. Both Co20%-ZIF-8 and Fe₃O₄/MCC/Co20%-ZIF-8 exhibited similar and remarkable photocatalytic activity under visible light (achieving 97% MB removal). The mechanism of photodegradation of MB by Fe₃O₄/MCC/Co20%-ZIF-8 was studied, revealing a first-order degradation kinetics (k = 13.78 × 10^–3 min^–1), with peroxide and hole species as the predominant active reagents. The magnetic composite successfully displayed recyclability and reusability over multiple cycles with negligible reduction in MB photodegradation efficiency.