Litchi-like Sn-MOF derived SnS2@SC composite as an advanced anode material for Lithium-Ion batteries

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Xin Zhou, Qianqian Wu, Enwang Ma, Huizhong Xu, Yufeng Zhu, Minghui Zhao, Jianjian Lin, Wei Li
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Abstract

Tin-based metal materials are promising anode candidates for lithium-ion batteries due to their high theoretical capacity. However, their practical application is constrained by significant volume expansion, structural degradation, and slow electron transfer kinetics. In this study, a lyotropic Sn-MOF was synthesized using tin sulfate and terephthalic acid as the tin source and organic ligand. The lychee-like Sn-MOF was then utilized as a precursor to prepare a hollow porous SnS2@SC composite containing S-doped carbon through a hydrothermal method. The SnS2@SC composite features nanoflower-like SnS2 embedded in a carbon skeleton, which increases the specific surface area, while the hollow structure derived from the Sn-MOF provides an efficient conductive network and buffer space to enhance electrochemical performance. As a result, the SnS2@SC electrode exhibits an impressive initial discharge capacity of 1062.9 mAh g−1 at 0.1 A g-1 and excellent long-term cycling stability, retaining 689.5 mAh g−1 at 2.0 A g-1 after prolonged cycling. This study offers a viable strategy for the rational design of bimetallic sulfide heterostructures and provides insights into the development of advanced electrochemical applications.

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来源期刊
Applied Surface Science
Applied Surface Science 工程技术-材料科学:膜
CiteScore
12.50
自引率
7.50%
发文量
3393
审稿时长
67 days
期刊介绍: Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.
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