A supramolecular polydimethysiloxane-based coating with tunable surface topography for photothermal-enhanced sterilization, self-healing and anti/de-icing

IF 13.3 1区 工程技术 Q1 ENGINEERING, CHEMICAL
Chaojie Shen, Xiaoyong Qiu, Peipei Zhang, Jing Liu, Zekai Zhang, Bowen Dong, Hanlian Liu, Chuanzhen Huang, Jun Huang, Xin Cui
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引用次数: 0

Abstract

Supramolecular polydimethylsiloxane (PDMS)-based materials have been receiving enormous research attention owing to their distinct properties such as intrinsic hydrophobicity, low toxicity and self-healing ability, which are in great demand in various applications. However, it remains challenging to endow them with multiple functions and maintain or even enhance their original attributes simultaneously. Here, a novel polymer coating is designed and fabricated by incorporating photothermal ferrosoferric oxide nanoparticles (Fe3O4 NPs) with a supramolecular PDMS network dynamically crosslinked via intramolecular imine bonding and intermolecular hydrogen bonding. Under the superior photothermal effect induced by near-infrared (NIR) light, the prepared coating exhibits significantly improved sterilization, self-healing and anti/de-icing capabilities, and specifically, the sterilization efficiency can reach up to 99.4 %, the deep cut can heal completely within 50 s, the ice-free state can be expected to sustain permanently, and the accreted ice can be fully melted within 2 min. Moreover, the surface topography of this thermoplastic coating can be customized through a facile template-based secondary processing for adaptive wettability even superhydrophobicity (water contact angle ∼155.9°, sliding angle ∼4°), which could further amplify its anti-icing and other properties. Our work opens a new path to develop versatile polymer coatings for diverse applications.

Abstract Image

一种表面形貌可调的超分子聚二甲基硅氧烷涂层,用于光热增强杀菌、自愈和防除冰
超分子聚二甲基硅氧烷(PDMS)基材料由于其固有的疏水性、低毒性和自愈能力等独特的性能而受到广泛的研究关注,在各种应用领域都有很大的需求。然而,如何赋予它们多种功能,同时保持甚至增强它们原有的属性,仍然是一个挑战。本文设计并制备了一种新型聚合物涂层,该涂层将光热氧化铁纳米颗粒(Fe3O4 NPs)与超分子PDMS网络结合,通过分子内亚胺键和分子间氢键动态交联。在近红外(NIR)光诱导的优越光热效应下,制备的涂层表现出显著提高的杀菌、自愈和抗除冰能力,其中杀菌效率可达99.4 %,深切口可在50 s内完全愈合,无冰状态可预期永久维持,增冰可在2 min内完全融化。此外,这种热塑性涂层的表面形貌可以通过简单的基于模板的二次加工来定制,以获得自适应润湿性甚至超疏水性(水接触角~ 155.9°,滑动角~ 4°),这可以进一步增强其防冰和其他性能。我们的工作为开发多用途聚合物涂层开辟了一条新途径。
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来源期刊
Chemical Engineering Journal
Chemical Engineering Journal 工程技术-工程:化工
CiteScore
21.70
自引率
9.30%
发文量
6781
审稿时长
2.4 months
期刊介绍: The Chemical Engineering Journal is an international research journal that invites contributions of original and novel fundamental research. It aims to provide an international platform for presenting original fundamental research, interpretative reviews, and discussions on new developments in chemical engineering. The journal welcomes papers that describe novel theory and its practical application, as well as those that demonstrate the transfer of techniques from other disciplines. It also welcomes reports on carefully conducted experimental work that is soundly interpreted. The main focus of the journal is on original and rigorous research results that have broad significance. The Catalysis section within the Chemical Engineering Journal focuses specifically on Experimental and Theoretical studies in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. These studies have industrial impact on various sectors such as chemicals, energy, materials, foods, healthcare, and environmental protection.
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