Jiaxing Liu, Zan Wang, Zhihao Yang, Meiling Liu, Hongtao Liu
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引用次数: 0
Abstract
This study presents the synthesis of a transparent, flexible gel polymer electrolyte (GPE) based on the protic ionic liquid BMImHSO4 and on polyvinyl alcohol (PVA) through solution casting and electrochemical evaluation in a 2.5 V symmetrical C/C electrical double-layer solid-state capacitor (EDLC). The freestanding GPE film exhibits high thermal stability (>300 °C), wide electrochemical windows (>2.7 V), and good ionic conductivity (2.43 × 10-2 S cm-1 at 20 °C). EDLC, using this novel GPE film, shows high specific capacitance (81 F g-1) as well as good retention above 90% of the initial capacitance after 4500 cycles. The engineered protic ionic liquid GPE is, hopefully, applicable to high-performance solid-state electrochemical energy storage.
期刊介绍:
Materials (ISSN 1996-1944) is an open access journal of related scientific research and technology development. It publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Materials provides a forum for publishing papers which advance the in-depth understanding of the relationship between the structure, the properties or the functions of all kinds of materials. Chemical syntheses, chemical structures and mechanical, chemical, electronic, magnetic and optical properties and various applications will be considered.