{"title":"Emission enhancement in a luminescent polychlorinated diphenylpyridylmethyl radical through coordination to silver(I)","authors":"Takuto Mibu, Ryota Matsuoka, Masanari Nagasaka, Tetsuro Kusamoto","doi":"10.1039/d4dt03129f","DOIUrl":null,"url":null,"abstract":"A luminescent silver(<small>I</small>) complex containing a luminescent radical ligand was prepared for the first time. Coordination to Ag<small><sup>I</sup></small> enhanced and red-shifted the radical-centered emission. This study demonstrates similar effects in the luminescence of the radical by complexation with group 11 d<small><sup>10</sup></small>-metal ions.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":"38 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4dt03129f","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
A luminescent silver(I) complex containing a luminescent radical ligand was prepared for the first time. Coordination to AgI enhanced and red-shifted the radical-centered emission. This study demonstrates similar effects in the luminescence of the radical by complexation with group 11 d10-metal ions.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.