Machine Learning Approach for the Prediction of Biomass Waste Pyrolysis Kinetics from Preliminary Analysis.

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2024-11-25 eCollection Date: 2024-12-10 DOI:10.1021/acsomega.4c04649
Kai Xiao, Xianghui Zhu
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引用次数: 0

Abstract

In the present work, artificial neural network (ANN)-based machine learning models are developed to predict biomass pyrolysis kinetics. Data sets of thermogravimetric analysis and feedstock characterization from a diverse range of biomasses were used to build and test the networks. The composition of the raw biomass material was classified and used as input parameters of ANN models. Three models, which use ultimate analysis, proximate analysis, and three components as input parameters, were developed in this study. A total of 32 types of biomass raw materials were used, and 270 sets of kinetic data were obtained according to different pyrolysis conversion rates ranging from 0.1 to 0.9. Results show that increasing the number of neurons can improve the prediction accuracy. The optimized neuron number is 7-11. The largest relative deviation between experimental and modeling results for the three models are 20.80%, 14.06% and 12.85%, respectively, which proves that using cellulose, hemicellulose, and lignin as input parameters of the neural network model can better predict the activation energy of pyrolysis at each reaction stage. The particle swarm optimization algorithm could significantly improve the prediction accuracy of the BP-ANN model. The largest deviation for activated energy prediction decreases from 12.85% to 6.72%.

通过初步分析预测生物质废物热解动力学的机器学习方法。
本研究开发了基于人工神经网络(ANN)的机器学习模型,用于预测生物质热解动力学。热重分析和各种生物质原料表征的数据集被用来构建和测试网络。对生物质原料的成分进行了分类,并将其作为 ANN 模型的输入参数。本研究开发了三种模型,分别使用终极分析、近似分析和三种成分作为输入参数。共使用了 32 种生物质原料,并根据 0.1 至 0.9 的不同热解转化率获得了 270 组动力学数据。结果表明,增加神经元数量可以提高预测精度。优化的神经元数目为 7-11。三个模型的实验结果与建模结果的最大相对偏差分别为 20.80%、14.06% 和 12.85%,这证明将纤维素、半纤维素和木质素作为神经网络模型的输入参数可以更好地预测各反应阶段的热解活化能。粒子群优化算法可以显著提高 BP-ANN 模型的预测精度。活化能预测的最大偏差从 12.85% 降至 6.72%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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