Characterization of freshwater sludge generated in Singapore: exploring opportunities for a circular economy

Bo Xu, Junde Qin, Mingqian Yang, Yaolin Yi
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Abstract

Freshwater sludge (FS), a by-product of drinking water treatment, is produced in large quantities globally but remains underutilized, predominantly ending up in landfills. As landfill space becomes increasingly scarce and environmental regulations tighten, there is an urgent need for sustainable management strategies for FS. By adopting circular economy principles that emphasize reuse and recycling, potential solutions can be found. This study analyzed the chemical and mineral compositions as well as leaching behavior of ten FS batches collected from various Singapore waterworks. It explored the potential applications of FS, addressing challenges and proposing solutions for its repurposing. The results revealed that FS primarily consists of aluminum oxide (34.94%–57.2%), sulfur trioxide (5.56%–8.98%), and silicon dioxide (1.24%–6.85%). FS also contains minerals such as aluminum sulfate, bayerite, kaolinite, and quartz. The primary variation among different batches of FS was the organic content (28.89%–52.3%), which mainly consisted of carbon, hydrogen, and oxygen. The leaching test indicated that the heavy metal concentrations in FS were within safe limits, suggesting its safety for various applications, especially in high pH environments. The substantial organic content of FS makes it a candidate for conversion into biochar and hydrochar for soil amendment. The rich aluminum content in FS opens avenues for its application in construction material fabrication, soil enhancement, and the remediation of heavy metal-laden wastes, soils, and wastewater.

Graphical abstract

新加坡淡水污泥的特征:探索循环经济的机遇
淡水污泥(FS)是饮用水处理过程中产生的一种副产品,在全球范围内产量巨大,但一直未得到充分利用,主要被填埋。随着垃圾填埋空间的日益稀缺和环保法规的不断收紧,亟需制定可持续的污泥管理策略。通过采用强调再利用和再循环的循环经济原则,可以找到潜在的解决方案。本研究分析了从新加坡不同水厂收集的十批 FS 的化学和矿物成分以及浸出行为。研究探讨了FS的潜在应用,应对了FS再利用所面临的挑战,并提出了解决方案。研究结果表明,FS 主要由氧化铝(34.94%-57.2%)、三氧化硫(5.56%-8.98%)和二氧化硅(1.24%-6.85%)组成。FS 还含有硫酸铝、贝叶石、高岭石和石英等矿物。不同批次 FS 之间的主要差异在于有机物含量(28.89%-52.3%),主要由碳、氢和氧组成。浸出测试表明,FS 中的重金属浓度在安全范围内,这表明它在各种应用中都是安全的,尤其是在高 pH 值环境中。FS 中大量的有机物含量使其成为转化为生物炭和水炭用于土壤改良的候选材料。FS 中丰富的铝含量为其在建筑材料制造、土壤改良以及重金属废物、土壤和废水修复方面的应用开辟了道路。
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