Lattice Modulation on Singlet‐Triplet Splitting of Silver Cluster Boosting Near‐Unity Photoluminescence Quantum Yield

IF 16.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Wei-Dong Tian, Chengkai Zhang, Sayan Paul, Wei-Dan Si, Zhi Wang, Pan-Pan Sun, Anakuthil Anoop, Chen-Ho Tung, Di Sun
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引用次数: 0

Abstract

Developing thermally activated delayed fluorescence (TADF)‐active silver clusters with near‐unity quantum efficiency is of practical importance in cutting‐edge optoelectronic devices, but remains a tremendous challenge due to the difficulty of de novo synthesis and uncertainty of properties. Herein, we demonstrate a lattice modulation on parent TADF‐activate silver cluster, acheving TADF‐driven photoluminescence quantum yield (PLQY) from 12% to near‐unity. Systematic experimental and calculated results reveal that the lattice modulation effectively lower the singlet‐triplet splitting (ΔEST) from 718 to 549 cm‐1, thereby facilitating thermally activated reverse intersystem crossing: T5→S5, leading to extremely efficient TADF by surpassing both phosphorescence and non‐radiative decay, thus boosting the near‐unity PLQY. Such high PLQY are extremely rare in the TADF‐active silver clusters and even in the whole noble‐metal clusters. This research showcases an unparalleled example of lattice modulation to realize near unity PLQY of TADF‐active silver clusters.
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来源期刊
CiteScore
26.60
自引率
6.60%
发文量
3549
审稿时长
1.5 months
期刊介绍: Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.
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