Calcium Chemistry as a New Member of Post‐Lithium Battery Family: What Can We Learn from Sodium and Magnesium

IF 16.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Zhenyou Li, Shuangshuang Cui, Joachim Häcker, Maryam Nojabaee, Maximilian Fichtner, Guanglei Cui, Zhirong Zhao-Karger
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Abstract

Next‐generation battery technologies need to consider their environmental impact throughout the whole cycle life, which has brought new chemistries based on earth‐abundant elements to the spotlight. Rechargeable calcium batteries are such an emerging technology, which shows the potential to provide high cell voltage and high energy density close to lithium‐ion batteries. Additionally, the use of Ca2+ as a charge carrier renders significant sustainable values. Although pioneering work on the electrochemistry of Ca has been carried out for more than half a century, demonstration of reversible Ca chemistries in non‐aqueous media was only achieved within the past decade. In this review, we will present recent development of rechargeable calcium batteries, focusing on mainly the similarities but also differences between Ca chemistry and other post‐lithium chemistry. According to the periodic nature of elements, magnesium (an alkaline earth element as Ca) and sodium (a diagonally adjacent element to Ca) have similar chemical properties to Ca in various aspects. We shall elaborate on how the solution chemistry, metal behaviors and transport mechanisms of Ca can be better understood in light of the established principles in the respective Mg/Na systems. We hope the discussion will inspire synergetic development between Ca batteries and other post‐lithium systems.
作为后锂电池家族新成员的钙化学:我们能从钠和镁中学到什么
下一代电池技术需要考虑其在整个循环寿命期间对环境的影响,这使得基于地球丰富元素的新化学物质成为关注的焦点。可充电钙电池就是这样一种新兴技术,它具有提供接近锂离子电池的高电池电压和高能量密度的潜力。此外,使用 Ca2+ 作为电荷载体还具有重要的可持续价值。虽然有关 Ca 电化学的开创性工作已经进行了半个多世纪,但在非水介质中实现可逆 Ca 化学反应的工作仅在过去十年中完成。在这篇综述中,我们将介绍可充电钙电池的最新发展,主要关注钙化学与其他后锂化学之间的相似之处,同时也关注它们之间的不同之处。根据元素周期律,镁(与钙同属碱土元素)和钠(与钙斜邻的元素)在各方面都具有与钙相似的化学性质。我们将详细阐述如何根据镁/钠体系各自的既定原理更好地理解 Ca 的溶液化学、金属行为和传输机制。我们希望这些讨论能激发钙电池和其他后锂系统之间的协同发展。
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来源期刊
CiteScore
26.60
自引率
6.60%
发文量
3549
审稿时长
1.5 months
期刊介绍: Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.
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