Bioinspired tree-like electroactive poly(lactic acid) nanofibers with enhanced surface activity and interfacial polarization for intelligent health management

IF 8.1 1区 工程技术 Q1 ENGINEERING, CHEMICAL
Mengyuan Shen , Jiaqi Li , Lv Ke , Yifan Zhang , Guiying Zhu , Xiang Li , Jia-Qiong Li , Jiang Shao , Xinjian He , Mingming Zhang , Huan Xu
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引用次数: 0

Abstract

Poly(lactic acid) (PLA)-based nanofibrous membranes (NFMs) have significant potential for use in biodegradable filters for air purification, but their application is often limited by relatively poor electret properties. Herein, tree-inspired gradient PLA (TG-PLA) nanofibers with biomimetic surfaces and remarkable electroactivity were fabricated by coaxial electrospinning of a unique core–shell structure. Importantly, the bioinspired structure conferred dramatic increase of dielectric constant for TG-PLA NFMs by 218 %, as well as enhanced in situ electret properties (over 3-fold rise of surface potential). The well-controlled morphological features and increased electroactivity contributed synergistically to distinct promotion of active PM-capturing performance, as exemplified by 99.25 % filtration of PM0.3 at the airflow velocity of 32 L/min for TG-PLA2, largely surpassing the counterpart (only 89.63 %). Benefiting from the significantly increased electroactivity, TG-PLA2 exhibited superior energy harvesting performance and long-term stability (output voltage of 44.7 V, over 2000-second cycle test). Furthermore, a convolutional neural network (CNN) algorithm was developed to establish an intelligent respiratory recognition system, demonstrating high-accuracy diagnosis of multiple complex scenarios. The exceptional promotion in the surface activity and intrinsic electroactivity for PLA nanofibers is of enormous potential for environmental applications. Our bioinspired strategy can lead to a versatile platform that integrates with profound property improvements and scale-up feasibility for intelligent protective membranes.

Abstract Image

Abstract Image

具有增强表面活性和界面极化的仿生树状电活性聚乳酸纳米纤维,用于智能健康管理
聚乳酸(PLA)基纳米纤维膜(NFMs)在可生物降解空气净化过滤器中具有重要的应用潜力,但其应用往往受到相对较差的驻极体性能的限制。本文采用同轴静电纺丝的方法制备了具有仿生表面和显著电活性的树形梯度聚乳酸(TG-PLA)纳米纤维。重要的是,生物启发结构使TG-PLA nfm的介电常数显著增加了218.0 %,并增强了原位驻极体特性(表面电位增加了3倍以上)。良好控制的形态特征和增加的电活性协同促进了活性pm捕获性能的显著提高,例如TG-PLA2在32 L/min的风速下对PM0.3的过滤率为99.25 %,大大超过了对应的89.63 %。得益于显著增加的电活性,TG-PLA2表现出优异的能量收集性能和长期稳定性(输出电压44.7 V,超过2000秒循环测试)。此外,开发了卷积神经网络(CNN)算法,建立了智能呼吸识别系统,实现了对多种复杂场景的高精度诊断。PLA纳米纤维的表面活性和本征电活性的显著提高,在环境应用方面具有巨大的潜力。我们的生物启发策略可以导致一个多功能平台,集成了深刻的性能改进和扩大智能保护膜的可行性。
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来源期刊
Separation and Purification Technology
Separation and Purification Technology 工程技术-工程:化工
CiteScore
14.00
自引率
12.80%
发文量
2347
审稿时长
43 days
期刊介绍: Separation and Purification Technology is a premier journal committed to sharing innovative methods for separation and purification in chemical and environmental engineering, encompassing both homogeneous solutions and heterogeneous mixtures. Our scope includes the separation and/or purification of liquids, vapors, and gases, as well as carbon capture and separation techniques. However, it's important to note that methods solely intended for analytical purposes are not within the scope of the journal. Additionally, disciplines such as soil science, polymer science, and metallurgy fall outside the purview of Separation and Purification Technology. Join us in advancing the field of separation and purification methods for sustainable solutions in chemical and environmental engineering.
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