Zhen Wang, Zhenlu Li, Xinfeng Lin, Long Zheng, Ziwei Li, Shaorong Lu
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引用次数: 0
Abstract
Non-covalent modification of fillers with hyperdispersants in composite processing avoids destroying the regular structure of the filler and is simpler and easier to operate than ordinary surface modification methods. A novel hyperdispersant, GI-g-PHA, was synthesized by esterification of poly12-hydroxystearic acid (PHA) and glycerol (GI) to improve the thermal conductivity (TC) and tensile properties of natural rubber (NR)/boron nitride (BN) composites. After the addition of 5 wt% hyperdispersant, the thermal conductivity of 20 vol% and 25 vol% BN composites was 0.965 W/mK and 1.364 W/mK, respectively, which was 9.6 and 13.6 times higher than that of NR matrix (0.1 W/mK). Molecular dynamics simulations showed an increase in molecular binding energy and a decrease in free volume fraction after the addition of dispersant, which provided a microscopic explanation for the change in compatibility. This study provides a way to prepare polymer matrix composites with high thermal conductivity and high strength.
期刊介绍:
Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics.
The main scope is covered but not limited to the following core areas:
Polymer Materials
Nanocomposites and hybrid nanomaterials
Polymer blends, films, fibres, networks and porous materials
Physical Characterization
Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films
Polymer Engineering
Advanced multiscale processing methods
Polymer Synthesis, Modification and Self-assembly
Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization
Technological Applications
Polymers for energy generation and storage
Polymer membranes for separation technology
Polymers for opto- and microelectronics.