Tuning specific absorption rate of Mn ferrite nanoparticles synthesized by a thermal decomposition method with different Mn concentrations.

IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Sahar Oroujizad, Mohammad Almasi Kashi, Amir H Montazer
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引用次数: 0

Abstract

A thermal decomposition method is used to synthesize monodisperse Mn ferrite nanoparticles (NPs) by changing Mn concentration from 0.1 to 0.8 mmol. The effects of Mn concentration on structural, compositional, morphological, magnetic, and hyperthermia properties are investigated. Transmission electron microscopic images show that the morphology of the NPs changes from flower-like to polygonal with increasing the Mn concentration. The saturation magnetization reaches a maximum value of 48.32 emu/g and a minimum value of 11.09 emu/g with changing the Mn concentration, whereas the coercivity value decreases from 12.6 to 5.3 Oe. The first-order reversal curve (FORC) analysis enables the estimation of superparamagnetic contribution of the Mn ferrite NPs in the range of 21-59.5%. The highest specific absorption rate (SAR) value is obtained to be 385.37 W/g for Mn0.1Fe2.9O4 NPs with the maximum superparamagnetic contribution using a manganese concentration of 0.4 mmol.

采用热分解法合成单分散锰铁氧体纳米粒子(NPs),锰的浓度从 0.1 mmol 到 0.8 mmol 不等。研究了锰浓度对结构、组成、形貌、磁性和热性能的影响。透射电子显微镜图像显示,随着锰浓度的增加,纳米粒子的形态从花朵状变为多边形。随着锰浓度的变化,饱和磁化率的最大值为 48.32 emu/g,最小值为 11.09 emu/g,而矫顽力值则从 12.6 降至 5.3 Oe。通过一阶反转曲线(FORC)分析,可以估算出锰铁氧体 NPs 的超顺磁性贡献率在 21-59.5% 之间。锰浓度为 0.4 mmol 时,Mn0.1Fe2.9O4 NPs 的最高比吸收率(SAR)值为 385.37 W/g,超顺磁性贡献最大。
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来源期刊
Nanotechnology
Nanotechnology 工程技术-材料科学:综合
CiteScore
7.10
自引率
5.70%
发文量
820
审稿时长
2.5 months
期刊介绍: The journal aims to publish papers at the forefront of nanoscale science and technology and especially those of an interdisciplinary nature. Here, nanotechnology is taken to include the ability to individually address, control, and modify structures, materials and devices with nanometre precision, and the synthesis of such structures into systems of micro- and macroscopic dimensions such as MEMS based devices. It encompasses the understanding of the fundamental physics, chemistry, biology and technology of nanometre-scale objects and how such objects can be used in the areas of computation, sensors, nanostructured materials and nano-biotechnology.
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