Construction and Magnetic Difference of {CoIIICoII12MII6} (M = CoII/CdII) Aggregates with Homo- and Heterometallic Centers Derived from {Co14} Precursors

IF 4.3 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2024-12-12 DOI:10.1021/acs.inorgchem.4c04083

Ye Tao, Yun-Kai Chen, Huang-Fei Qin, Zhao-Ting Pan, Hai-Ye Li, Haiquan Tian, Fu-Ping Huang

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引用次数: 0

Abstract

Controllable synthesis of sophisticated aggregations has attracted wide attention from scientists. In this work, homo- and heterometallic {Co^IIICo^II₁₂M^II₆} (M = Co^II/Cd^II) aggregates with similar skeletons, composed of two [Co₃M₃(dpbt)₃] peripheries and a central [Co₇(OH)₈] vertex-fused double-cubane, were constructed from prefabricated {Co₁₄} clusters and characterized by single-crystal X-ray diffraction and XPS, ICP-MS, SEM (EDX), and so on. And then, the structure and magnetic differences of them had been further analyzed under dotted with paramagnetic Co^II ions and/or diamagnetic Cd^II ions. Interestingly, the spin canting behavior in {Co^IIICo^II₁₈} was suppressed in {Co^IIICo^II₁₂Cd^II₆}, upon the introducing of Cd^II ions.

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.