Unconventional Fluorescent Magnetic Mesoporous Microspheres for Visualizing Latent Fingerprints

IF 18.5 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Ruijia Chen, Fei Fan, Liang Peng, Xuejun Zhao, Jing Zhao, Chen Lv, Pingyong Liao, Keming Lu, Tingting Qiu, Lu Xiao, Yan Lu, Shang Xue, Guanglei Zhou, Wenbin Liu
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Abstract

High-resolution visualization of latent fingerprints is key to effectively assessing crime scenes. Unconventional luminophores provide promising application potentials due to facile preparation and excellent biocompatibility, but are rarely reported for imaging latent fingerprints (LFPs). Here, a novel and cost-effective strategy is developed to prepare unconventional fluorescent magnetic mesoporous microspheres (UFMMMs) by growing a mesoporous silicon shell, templated by designed amphipathic unconventional luminescent (N-eicosanoyl-hydroxyproline, C20-HYP) aggregate micelles, on the magnetite core. The obtained UFMMMs with blue unconventional fluorescence and an average diameter of 650 nm can clearly visualize the level 1–3 details of LFPs on different substrates. The outstanding capability in imaging fingerprints results from the combined effects of the fine luminescence, paramagnetism, and high dispersion of UFMMMs. The intermolecular interactions between C20-HYP and amino in UFMMMs enhance the fluorescence intensity by increasing electron delocalization and the proportion of π-electrons. This study provides a new perspective for the controllable construction of fluorescent probes based on unconventional luminophores.

Abstract Image

潜伏指纹的高分辨率可视化是有效评估犯罪现场的关键。非常规发光体具有制备简便、生物相容性好等优点,具有广阔的应用前景,但用于潜伏指纹(LFP)成像的报道却很少。本文开发了一种新颖且经济高效的策略,通过在磁铁矿内核上生长介孔硅外壳(由设计的两性非常规发光(N-二十碳酰-羟脯氨酸,C20-HYP)聚合胶束模板化)来制备非常规荧光磁性介孔微球(UFMMMs)。所获得的 UFMMMs 具有蓝色非常规荧光,平均直径为 650 nm,可清晰显示不同基底上 LFP 的 1-3 级细节。UFMMMs 的精细发光、顺磁性和高分散性共同作用,造就了其在指纹成像方面的卓越能力。UFMMMs 中 C20-HYP 与氨基之间的分子间相互作用通过增加电子析出和 π 电子比例来增强荧光强度。这项研究为基于非常规发光体构建可控荧光探针提供了新的视角。
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来源期刊
Advanced Functional Materials
Advanced Functional Materials 工程技术-材料科学:综合
CiteScore
29.50
自引率
4.20%
发文量
2086
审稿时长
2.1 months
期刊介绍: Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week. Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.
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